The (0001) surface of a-Mo2C prepared by Ar ion bombardment and annealing was characterized using X-ray photoelectron spectroscopy and low energy electron diffraction (LEED). An ion-bombarded surface annealed to 1000 K exhibits an Mo/C ratio of 2.2, characteristic of an Mo-terminated surface. The Mo-terminated surface exhibits a complex, but predominantly ‘(1×1)’ hexagonal LEED pattern on a dif...