Mortality rates of eggs and nauplii are essential for understanding and modelling dynamics of copepod populations. Abundances of Calanus finmarchicus females, eggs and nauplii were determined at 88 stations in the Labrador Sea. Egg production rates (EPRs) and egg and naupliar stage durations were calculated using published relationships with in situ chlorophyll concentration and temperature. Th...

Density functional theory (DFT) calculations have been used to study the oxidative addition of aryl halides to complexes of the type [Ni(PMen Ph(3-n) )4 ], revealing the crucial role of an open-shell singlet transition state for halide abstraction. The formation of NiI versus NiII has been rationalised through the study of three different pathways: (i) halide abstraction by [Ni(PMen Ph(3-n) )3 ...

in the current investigation a novel nano hybrid adsorbent mcm-41/n-(3-trimethoxysilyl)-propyl)diethylenetriamine (mcm-41/tmspdeta) was prepared and was characterized using dls (dynamic light scattering), fourier transform infrared (ftir), x-ray diffraction (xrd), brunauer–emmett–teller (bet) analytical techniques and transmission electron microscopy (tem). the synthesized mcm-41/tmspdeta adsor...

A family of terbium probes was synthesized and evaluated for the luminescence detection of copper and zinc in water at neutral pH. Each probe incorporates a terbium ion chelated by a macrocyclic polyaminocarboxylate and conjugated to either one, two, or three phenanthridine antennas via a diamine linker. All three probes, Tb-1Phen, Tb-2Phen, and Tb-3Phen, exhibit similar responses toward copper...

Five coordinated novel complexes of CuII and NiII have been synthesized from benzil and 1,3- diaminopropane-CuII/NiII complex and characterized by elemental analysis, i.r., n.m.r., e.p.r, molar conductance and u.v-vis, spectroscopy. The complexes are ionic in nature and exhibit pentaeoordinated geometry around the metal ion. The reaction kinetics of C25H36N5O2CuCl with calf thymus DNA was studi...

The resolutions of metal-4-(2-pyridylazo)resorcinol chelates by capillary zone electrophoresis (CZE) were investigated in the presence of some interacting reagents; also, equilibrium reactions between the chelates and the interacting reagents were analyzed in an aqueous solution. Among nine metal chelates formed in aqueous solution, the chelates of VV, FeII, CoIII, NiII, and CuII were resolved ...

This paper reports on a series of five chiral Schiff base push-pull compounds derived from enantiomerically pure (1R,2R)-(?)-1,2-diaminocyclohexane. The NiII, CuII, ZnII and PdII complexes supported by ferrocene-containing unsymmetrically-substituted N2O2 quadridentate ligand were prepared via template reactions isolated in 74–87 % yields. A combination EA, IR, UV/vis 1H/13C{1H} NMR spectroscop...

besides human dental and skeletal fluorosis, drinking water above permissible levels of fluoride is known to cause a wide range of adverse health effects. in this study, the adsorption of fluoride from aqueous solution onto pretreated zeolite has been studied by using batch test. the large surface area of natural zeolite (i. e., clinoptilolite from miyaneh region, iran) was utilized to create a...

Diamond-like carbon (DLC) films have been successfully deposited on Ti-50.8 at.%Ni using plasma based ion implantation (PBII) technique. The influences of the pulsed negative bias voltage applied to the substrate from 12 kV to 40 kV on the structure, nano-indentation hardness and Young’s modulus are investigated by the X-ray photoelectron spectroscopy (XPS) and nano-indentation technique. The r...

dft calculations were used to investigate adsorptionof  f-, cl-, li+ and na+ ions on the exterior surface of mg12o12 nanocage in the gas phase and water media. the most favorite position for adsorption of the studied anions and cations are atop of mg and o atoms of mg12o12, respectively. the strongest interaction is obtained when fluoride is located atop of mg atom with the adsorption energy of...