Secondary phosphine oxides react with vinyl sulfides (both alkyl- and aryl-substituted sulfides) under aerobic and solvent-free conditions (80 °C, air, 7-30 h) to afford 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides in 70-93% yields.

Double refractory gold concentrates were subjected a two-stage microbial process to destroy both sulfides and carbonaceous matter. In the first stage, the well-known sulfide biooxidation process, which utilizes chemolithotrophic bacteria was used to oxidize sulfides and in the second stage carbonaceous matter is destroyed using the bacterium Streptomyces setonii. After biooxidation of sulfides ...

Thiocyanates and trifluoromethyl sulfides are important compounds and have classically been synthesized via multistep procedures together with the formation of significant amounts of byproducts. Herein, we demonstrate an oxidative nucleophilic strategy for the synthesis of thiocyanates and trifluoromethyl sulfides from thiol starting materials using nucleophilic reagents such as TMSCN and TMSCF...

We present and discuss the detection, through mid IR spectroscopy, of iron sulfides in the carbon rich ejecta of evolved stars. We find the spectroscopic signature of iron sulfides at 23 μm. We also find weak features at ∼34, 38 and 44 μm. The positions of these features correspond well with the resonances of the iron sulfide troilite. However, the relative strength of the 23 μm versus the othe...

The initial transgressive phase at the Leg 144 Guyots is characterized by a typical association of sedimentary facies (from bottom to top): in situ weathered volcanic rocks; variegated clays, partly pyritic; gray clay, pyritic, homogeneous, or mottled; black clay, peaty, laminated, or bioturbated; and marine argillaceous limestone. Site 877 at Wodejebato Guyot represents the typical development...

Abstract Background Organic pollutants at contaminated sites are often eliminated naturally by biological degradation. The redox processes responsible can be enhanced infiltrating electron acceptors such as nitrate or sulfate into the aquifer. However, addition of oxidative agents lead to undesired side-effects in saturated soil zone consumption oxidation sulfides contained Laboratory-scale 1D ...

This report presents the chemical and physical factors governing the generation of sulfur dioxide (SO2), its transformation into other sulfur compounds, and the removal of sulfur oxides within the cement kiln system. Sulfur in cement kilns is derived from both kiln feed and from the kiln fuel. The form of the sulfur dictates the location in the kiln where the SO2 generation takes place. Sulfur ...