نتایج جستجو برای: oligothiophene
تعداد نتایج: 259 فیلتر نتایج به سال:
Organic mixed valence compounds consisting of bisdiarylamino charge-bearing units with an oligothiophene bridge and oligothiophene radical cations have been compared using molecular modeling. The study has been performed with oligomers of 1 to 22 thiophene units. These two series of molecules have several properties in common, and intramolecular Single Electron Transfer (SET) in both series can...
Six new thiophene oligomers, here designated as tripodal-like oligothienyl-imidazoles, were synthesized and have been investigated in ethanol solution at room and low temperature. The oligomers bear a common core where two or more thiophenes are linked to one or more imidazole units that further links through its alpha-position to a different number of incremental thiophene units. The study inv...
A series of phenyl end-capped α-oligothiophenes containing four to seven thiophene subunits (4T–7T) was synthesized utilizing palladium-catalyzed cross-coupling reactions. UV/Vis spectroscopic analysis revealed one broad absorption band that shifts bathochromically with increasing number units. Structured emission spectra are observed Stokes shift ν~4000 cm−1 and quantum yields up 53%. End-capp...
In this work, we study the light absorption properties of different novel molecules based on benzo[1,2-b:4,5-b′]dithiophene (BDT), namely, BT-2F, BTRCl, and BTTzR, which hold great promise as electron-donor materials in organic solar cells. By employing density functional theory, electronic states related transitions these systems. Moreover, case observe that addition two three oligothiophene c...
One of the most challenging strategies to achieve tunable nanophotonic devices is to build robust nanohybrids with variable emission in the visible spectral range, while keeping the merits of pristine single-walled carbon nanotubes (SWNTs). This goal is realized by filling SWNTs ("pods") with a series of oligothiophene molecules ("peas"). The physical properties of these peapods are depicted by...
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