14 A [33_TD$DIFF]Airborne lead and acidic gasses are generated through combustion and mechanical abrasion of ammunition constituents during shooting events. Shooters and other personnel at shooting ranges are exposed to these airborne toxicants and the potential health risks of irritation, nervous system damage, and cancer. Past studies primarily focused on full-length work-shift exposure to le...

[1] Noble gas paleoclimate reconstructions from noble gas concentrations in groundwater have the promise of providing absolute paleotemperature information, but difficulties in modeling measured noble gas concentrations with simple models have led to a number of competing noble gas temperature (NGT) schemes being developed. These different models make different assumptions about the size and na...

Noble-gas chemistry has been undergoing a renaissance in recent years, due in large part to noble-gas hydrides, HNgY, where Ng = noble-gas atom and Y = electronegative fragment. These molecules are exceptional because of their relatively weak bonding and large dipole moments, which lead to strongly enhanced effects of the environment, complexation, and reactions. In this Account, we discuss the...

This review article surveys recent experimental and theoretical advances in the gas-phase ion chemistry of the noble gases. Covered issues include the interaction of the noble gases with metal and non-metal cations, the conceivable existence of covalent noble-gas anions, the occurrence of ion-molecule reactions involving singly-charged xenon cations, and the occurrence of bond-forming reactions...

An experimental system we developed combines triaxial rock deformation and mass spectrometry to measure noble gas flow before, during, and after rock fracture. Gas flow through a granite and basalt in its unfractured condition allows estimation of “native” permeability. Geogenic noble gas is released during triaxial deformation (real time) and is related to volume strain and acoustic emissions....