Various platinum-free electrocatalysts have been explored for hydrogen evolution reaction in acidic solutions. However, in economical water-alkali electrolysers, sluggish water dissociation kinetics (Volmer step) on platinum-free electrocatalysts results in poor hydrogen-production activities. Here we report a MoNi4 electrocatalyst supported by MoO2 cuboids on nickel foam (MoNi4/MoO2@Ni), which...

Four types of nickel catalysts supported on aluminum oxide (Ni/Al2O3) with different nickel loadings were synthesized using the co-precipitation method and were used for the hydrogenation of levulinic acid (LA) to prepare γ-valerolactone (GVL). The synthesized Ni/Al2O3 catalysts exhibited excellent catalytic activity in dioxane, and the activity of the catalysts was excellent even after being u...

A membranous shaped Ni/Zn layered double hydroxide based nanohybrid was obtained using a low-cost template-free hydrothermal process at optimized growth conditions of 180 °C for 6 h. The synthesized structurally, texturally and morphologically characterized different techniques such as X-ray diffraction, FTIR, XPS spectroscopy, BET analysis FESEM microscopy. adsorption performance our product e...

BACKGROUND Chromium (VI) has toxic and carcinogenic effects. So, determination and speciation of chromium in environmental samples is very important in view of health hazards. In this study, solid phase extraction (SPE) based on bulky amine-functionalized bimodal mesoporous silica nanoparticles (NH2-UVM-7) as a novel nanoadsorbent was applied for preconcentration and speciation of chromium (III...

toluene and benzene were eliminated using multi-walled carbon nanotubes (mwcnts). in order to investigate influence of acid treatment on the mwcnts adsorption capacities, the mwcnts were functionalized by nitric acid (10 m) under reflux conditions for 2 h. fourier transform infrared (ftir) and raman spectroscopy were employed to confirm the formation of functional groups on the nanotubes surfac...

Sucrose hydrogenolysis is industrially important for the production of polyols. To provide high glycerol yield under milder reaction conditions, a nickel catalyst promoted by Molybdenum and copper supported on kieselguhr was synthesized and optimized using Response Surface Methodology. A 3X5 experimental design has been adopted to study the effect of these constituents. A linear second-order mo...

Several reactions representing important categories of catalytic systems have been studied on chemically modified single crystal surfaces. These reactions are methanation of CO and CO:. hydrogenolysis of ethane. hydrogenation of ethylene. and q&propane ring-opening and hydrogenolysis. Poisoning of the above reactions by ordered. suhmonolayer coverages of sulfur shou large nonlinear effects for ...

−− The main objective of this work is to study the feasibility of new materials to be used as support for boron-nickel catalysts. Potential support materials such as: silica gel, alumina, hydrothermal modified Perlites and zeolite 4A, were characterized by BET, TPR and DRX. After the addition of Ni and B, their catalytic activity evaluated with the nitrobenzene hydrogenation model reaction. The...

BACKGROUND Metal alloys utilized in the management of jaw fractures may exert genotoxic effects. Our purpose was to compare the genotoxicity of intermaxillary fixation devices containing nickel and chromium to that of titanium miniplates utilized in treatment of jaw fractures through the analysis of sister chromatid exchange. METHODS In this prospective study, in a total of 28 non-smoker pati...