Different approaches like doping and sensitization have been used to develop photocatalysts that can lead to high reactivity under visible-light illumination, which would allow efficient utilization of solar irradiation and even interior lighting. We demonstrated a conceptually different approach by changing reaction route via introducing the idea of conventional Pd catalysis used in cross-coup...

We investigate the interaction of TbPc(2) single molecule magnets (SMMs) with ferromagnetic Ni substrates. Using element-resolved x-ray magnetic circular dichroism, we show that TbPc(2) couples antiferromagnetically to Ni films through ligand-mediated superexchange. This coupling is strongly anisotropic and can be manipulated by doping the interface with electron acceptor or donor atoms. We obs...

The Ni-doped ZrCo1−xNixSb half-Heusler compounds were prepared by arc-melting and spark plasma sintering technology. X-ray diffraction analysis results showed that all samples were crystallized in a half-Heusler phase. Thermoelectric properties of ZrCo1−xNixSb compounds were measured from room temperature to 850 K. The electrical conductivity and the absolute value of Seebeck coefficient increa...

Nickel nanoparticles loaded on the electron–proton mixed conductor BaCe0.5Zr0.3−xY0.2NixO3−δ (Ni/BCZYN, x = 0 and 0.03) were synthesized for use in the hydrogen electrode of a proton-conducting solid oxide electrolysis cell (SOEC). The Ni nanoparticles, synthesized by an impregnation method, were from 45.8 nm to 84.1 nm in diameter, and were highly dispersed on the BCZYN. The BCZYN nanoparticle...

Since the discovery of the metallic antiferromagnetic (AF) ground state near superconductivity in iron pnictide superconductors1–3, a central question has been whether magnetism in these materials arises from weakly correlated electrons4,5, as in the case of spin density wave in pure chromium6, requires strong electron correlations7, or can even be described in terms of localized electrons8,9 s...

Using density functional calculations, it is shown that pure MnN is stable in zincblende rather than in the experimentally reported distorted rocksalt structure. However, about 4% N vacancies are found to stabilize the rocksalt structure. It is found that C and O substitutions on N and Ga on Mn also favor rocksalt but Ni, SN, FeMn, and CoMn stabilize zincblende. This suggests that zincblende Mn...

Nitric oxide (NO) storage and release measurements have been recorded for Ni-doped CPO-27 (Mg) and CPO-27 (Zn), and the biological effect of the released NO was assessed in porcine coronary artery relaxation tests. The results indicate that the doping strategy leads to increased levels of NO storage and delivery compared to the parent materials and that the NO dosage and biological response can...

The microstructure of sputter deposited Ti-rich Ni-Ti thin films doped with Cu in the range 020.4 at.% and annealed for 1 h at 500 and 600°C has been investigated and correlated with the mechanical properties of the films measured by depth-sensing nanoindentation. X-ray diffraction analysis showed the microstructural evolution of Ni-Ti thin films when doped with Cu and annealed at different tem...

Gas selective sensors that are capable of sensing at hot-gas environment increasingly gaining importance for the monitoring combustion and thermal processes releasing NO, NO2 H2 containing hot gases temperatures exceeding 600 °C. Despite some drawbacks, TiO2 is operating as a gas sensor above 500 In this context, Ni-doped TiO2, Co-doped Rh-doped BaTiO3 have been prepared by oxalate coprecipitat...