Supramolecular assemblies involving interaction of a small organic molecule, 2-hydroxy-6-Naphthoic acid (HNA), with poly(styrene)-block-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymers are utilized to obtain micellar structures in solution, nanostructured thin films on flat substrates and, finally, nanoporous thin films. The formation of hydrogen bonds between HNA and the poly(4-vinylpyridi...

This project is a fundamental study into the development of low-cost, thin film solar cells. It explores the fabrication of semiconductor nanocomposites for photovoltaics using nanostructured inorganic materials and atomic layer deposition (ALD). In thin film technologies, there exists a common problem with conversion efficiency due to poor materials quality: the photogenerated electrons and ho...

Nanostructured magnetic materials are intensively investigated due to their unusual properties and promise for possible applications. The key issue for these materials is to understand the limits between their physical properties (transport, magnetism, mechanical, etc.) and their chemical–physical structure. In principle, a detailed knowledge of the chemical and physical structures allows calcu...

Nanostructured GaN materials, including nanowires and nanorods, are advantageous for nanoscale devices, owing to their higher surface-to-volume ratio than thin films. Despite the technological progress, there exist many issues be solved commercial applications. To realize nanostructured it is essential figure out thoroughly current transport mechanisms with regard contact size. Experimental the...

Artificial and engineered nanostructures expand the degrees of freedom with which one can manipulate the intricate interplay of light and matter. Certain nanostructural arrangements in the excited state enable the efficient electromagnetic coupling of propagating light with localized fields. Here, we demonstrate that light transmitted through a nanostructured metal thin film without any apertur...

Self-ordering growth of nanoarrays on strained metallic interfaces is an attractive option for preparing highly ordered nanotemplates. The great potential of this natural templating approach is that symmetry, feature sizes, and density are predicted to depend on the interfacial stress in these strained layers, which can be adjusted by changing the substrate-thin film composition, temperature, a...

The quartz/Al-ZnO film/nanostructured Al-ZnO/CdSe/Cu2O extremely thin absorber solar cell has been successfully realized. The Al-doped ZnO one-dimensional nanostructures on quartz templates covered by a sputtering Al-doped ZnO film was used as the n-type electrode. A 19- to 35-nm-thin layer of CdSe absorber was deposited by radio frequency magnetron sputtering, coating the ZnO nanostructures. T...

Ordered nanocone arrays of the electroactive polymer poly(3,4-ethylenedioxythiophene) (PEDOT) were fabricated by the simultaneous oxygen plasma etching of an electrodeposited PEDOT thin film coated with a hexagonally closed packed polystyrene bead monolayer. PEDOT nanocone arrays with an intercone spacing of 200 nm and an average nanocone height of 350 nm exhibited a low broadband reflectivity ...

Nanostructured active or absorbing layers of solar cells, including photonic crystals and wire arrays, have been increasingly explored as potential options to enhance performance of thin film solar cells because of their unique ability to control light. We show that 2D photonic crystals can improve light trapping by an enhanced density of optical states and improved incoupling, and demonstrate,...

Photocatalytic water splitting represents a promising way to produce renewable hydrogen fuel from solar energy. Ultrathin semiconductor electrodes for water splitting are of particular interest because the optical absorption occurs in the region where photogenerated charge carriers can effectively contribute to the chemical reactions on the surface. It is therefore important to manipulate and c...