Silicon materials remain unused for supercapacitors due to extreme reactivity of silicon with electrolytes. However, doped silicon materials boast a low mass density, excellent conductivity, a controllably etched nanoporous structure, and combined earth abundance and technological presence appealing to diverse energy storage frameworks. Here, we demonstrate a universal route to transform porous...

Proteolysis with proteases preloaded within nanopores of porous material is a very fast process, where proteins can be digested in minutes compared to the conventional bulk enzyme reactions taking place over hours. To model this surprising phenomenon, a modified sequential proteolytic mechanism has been developed to simulate the kinetics of the reaction. Digestion of myoglobin was used as an ex...

During recent years, major progress has been made in the understanding of the adsorption, pore condensation and hysteresis behavior of fluids in novel ordered nanoporous materials with well defined pore structure. This has led to major advances in the structural characterization by physical adsorption, also because of the development and availability of advanced theoretical procedures based on ...

Nanochemistry fabrication methods have improved remarkably over the last few years. Among the different strategies developed to elaborate nanomaterials, the templating method is one of the most attractive as it has proven to be reliable for the synthesis of arrays of nanowires and nanotubules of desired composition, sizes and aspect ratios. Chemical and electrochemical techniques are used for s...

Abstract Physisorption of hydrogen in nanoporous materials offers an efficient and competitive alternative for storage. At low temperatures (e.g. 77 K) moderate pressures (below 100 bar) molecular H 2 adsorbs reversibly, with very fast kinetics, at high density on the inner surfaces such as zeolites, activated carbons metal–organic frameworks (MOFs). This review, by experts Task 40 ‘Energy Stor...