BACKGROUND Gene transfer using non-viral vectors offers a non-immunogenic and safe method of gene delivery. Cellular uptake and intracellular trafficking of the nanoparticles can impact on the transfection efficiency of these vectors. Therefore, understanding the physicochemical properties that may influence the cellular uptake and the intracellular trafficking can aid the design of more effici...

Abstract Surfactant‐free one‐step redox reactions between two types of metal cations enable the synthesis core‐shell nanoparticles without sophisticated control. The reduced noble form a solid core, and transition dissolved upon oxidation induce subsequent formation oxide shell. Various nanostructures are obtained from combination reduction‐preferring Au 3+ , Pd 2+ Pt Rh Ir cations, oxidation‐p...

In the recent past, switchable surfactants and switchable/stimulus-responsive surface-active particles have been of great interest. Both can be transformed between surface-active and surface-inactive states via several triggers, making them recoverable and reusable afterward. However, the synthesis of these materials is complicated. In this paper we report a facile protocol to obtain responsive...

Tailoring the nano-morphology and nano-architecture of titanium dioxide (TiO₂) is the most important task in the third generation solar cells (Dye sensitized solar cells/Quantum dot sensitized solar cells) (DSSCs/QDSSCs). In this article we present complete study of surfactant free synthesis of TiO₂ nanostructures by a simple and promising hydrothermal route. The plethora of nanostructures like...

Combination of the surfactant-free nonaqueous sol–gel approach with the microwave technique makes it possible to synthesize Fe3O4, CoFe2O4, MnFe2O4, and NiFe2O4 nanoparticles of about 5–6 nm and with high crystallinity and good morphological uniformity. The synthesis involves the reaction of metal acetates or acetylacetonates as precursors with benzyl alcohol at 170 C under microwave irradiatio...

in this work needle like hydroxy apatite were synthesized in a reverse microemulsion droplets of water in cyclohexane, separated by a cationic surfactant and co-surfactant, in the presence of na-polyacrylate (paa) as an anionic polyelectrolyte. characterization of the as formed hap nanoparticles at the room temperature were carried out by x-ray diffraction (xrd) and fourier transform infrared s...

Colloidal GaP nanowires (NWs) were synthesized on a large scale by a surfactant-free, self-seeded solution-liquid-solid (SLS) method using triethylgallium and tris(trimethylsilyl)phosphine as precursors and a noncoordinating squalane solvent. Ga nanoscale droplets were generated in situ by thermal decomposition of the Ga precursor and subsequently promoted the NW growth. The GaP NWs were not in...

An electric field built inside a crystal was proposed to enhance photoinduced carrier separation for improving photocatalytic property of semiconductor photocatalysts. However, a static built-in electric field can easily be saturated by the free carriers due to electrostatic screening, and the enhancement of photocatalysis, thus, is halted. To overcome this problem, here, we propose sonophotoca...

We report in this paper novel chemistry that addresses the problem of surfactant solubility in supercritical CO2 for metal nanoparticle synthesis. This new approach for the preparation of organic-functionalized inorganic nanoparticles relies on the reduction of a metal precursor in a CO2-containing insoluble polymer. Reduction of the metal with H2 leads to small nanocrystals stabilized by the p...