BACKGROUND Repeated fracture of the denture base is a common problem in prosthodontics, and it represents a nuisance and a time sink for the clinician. Therefore, the possibility of increasing repair strength using new reinforcement materials is of great interest to prosthodontists. AIM OF THE STUDY This study aimed to evaluate the effects of incorporation of zirconia nanoparticles (nano-ZrO2...

This paper presents the results of mechanical strength of wet and dry zirconia/ Nafion® nano-composite membrane. The tensile tests were conducted to determine elastic modulus and stiffness of dry and wet pristine Nafion® membrane and modified Nafion® membrane. The composite membranes were prepared by recast method of different synthesized zirconium oxide with the zirconia content of 10% by weig...

Partially stabilized zirconia (PSZ) agglomerate toughened alumina has been prepared by the "deflocculation-flocculation" technique, using 2 and 3 mol. % Y2O3-doped zirconia powders. Samples containing up to about 30 vol.% zirconia were obtained. The resulting microstructure seems to be mainly influenced by the physical properties of the starting powders, e.g. agglomerate size and the specific s...

There is interest in using zirconia for biomedical applications as ball heads for total hip prostheses. Two potential types are under discussion: partially stabilized zirconia (PSZ) and tetragonal zirconia polycrystals (TZP) materials. Because of its enhanced material properties, TZP stabilized with yttria is favourable. To eliminate high amounts of natural radioactive impurities, the precursor...

A study was undertaken to evaluate the effect of artificial aging through steam and thermal treatment as influencing the shear bond strength between three different commercially available zirconia core materials, namely, Upcera, Ziecon, and Cercon, layered with VITA VM9 veneering ceramic using Universal Testing Machine. The mode of failure between zirconia and ceramic was further analyzed as ad...

BACKGROUND The aim of this study was to evaluate osteogenesis ability of CAD/CAM porous zirconia scaffolds enriched with hydroxy apatite used to augment large boney defects in a dog model. METHODS Surgical defects were made bilaterally on the lower jaw of 12 Beagle dogs. Cone beam CT images were used to create three dimensional images of the healed defects. Porous zirconia scaffolds were fabr...

Noble Gemini surfactants containing a siloxane moiety have been designed and successfully synthesized in the present study and are utilized as structure-directing agents for mesoporous metal oxides such as zirconia, titania, and vanadia. The siloxane moiety is believed to play an important nano-propping role during the surfactant removal by direct calcination, yielding thermally stable mesoporo...

A new derivative of zirconium (IV), [(acac)2Zr{ONC(Me)th-2}2] have been produced by treating bis(acetylacetonato)diisopropoxy zirconium(IV) with internally functionalised oxime HONC(Me)th-2 (where th = thiophene) in 1:2 stoichiometry, while refluxing in anhydrous toluene. After drying and purification, the product appeared as offwhite crystalline solid. Physico-chemical analysis of this derivat...

The effect of CaO on the formation of β- and γ-zirconia nanoparticles from α-zirconia was investigated and their stability evaluated via mechanical activation. α-ZrO2+8.5wt%CaO powder was milled for 2-150 hours with ball-to-powder weight ratios (BPWR) of 40:1 and 60:1. Structural evaluations were conducted using X-Ray diffraction and scanning electron microscope (SEM). Thermal analysis wa...