For a graph $G$ with edge set $E(G)$, the multiplicative sum Zagreb index of $G$ is defined as$Pi^*(G)=Pi_{uvin E(G)}[d_G(u)+d_G(v)]$, where $d_G(v)$ is the degree of vertex $v$ in $G$.In this paper, we first introduce some graph transformations that decreasethis index. In application, we identify the fourteen class of trees, with the first through fourteenth smallest multiplicative sum Zagreb ...