in the present study, a new gas diffusion electrode (gde) (based on pt/nafion membrane) is fabricated. the electrochemical results show that the new gde has the highest electrochemical activity toward the oxygen reduction reaction (orr) among the three electrodes. the sem and xrd findings show that a platinum layer can be attached to nafion membrane closely and firmly with a strong peak corresp...

Contact resistance among the components of a polymer exchange membrane fuel cell (PEMFC) has a crucial effect on cell performance. The geometry of the endplate plays an essential role in the contact pressure distribution over the membrane electrode assembly (MEA) and the amount of contact resistance between plates. In this work, the effects of endplate geometry on the contact pressure distribut...

A PVC membrane electrode based on 1-[({[(butylsulfunyl)carbothioyl]disulfanyl} carbothioyl)sulfanyl]butane as a suitable ion carrier for determination of lanthanum(III) ion was prepared. This electrode revealedsuch a good selectivity toward La3+ ion over a wide variety of other metal ions. Some experimental parametersuch as membrane composition, nature, and amount of plasticizer, the amount of ...

in the present study, we investigate the potentiometric behavior of cu2+ carbon paste electrodes based on two mercapto compounds 2-ethylmino-5-mercapto-1,3,4-thiadiazole (eamt) and 2-acetylamino-5-mercapto-1,3,4-thiadiazole (aamt) self-assembled on gold nano-paricle (gnp) as ionophore. then, the results obtained from the modified electrodes are compared. the self-assembled ionophores exhibit a ...

Performing carbon monoxide reduction in membrane electrode assembly configuration (MEA) is critical to achieving a high reaction rate while reducing cell resistance. Most studies examine the role of cathode on product selectivity and stability, comparatively little attention has been given impact performance. This study demonstrates that properties such as water uptake, ion-exchange capacity, f...

Numerical modeling has been a vital tool in proton-exchange-membrane fuel-cell (PEMFC) analysis; however, the predictive capabilities of these models depend on input physical parameters, several which are either not experimentally measured or have large scatter values. This article presents an uncertainty propagation-based sensitivity analysis to identify model parameters that impact prediction...