Syngenite (K2Ca(SO4)2 ⋅ H2O) presents an effective hydration activator (accelerator) for anhydrite (CaSO4) applied in construction systems. The current synthesis relies on co-precipitation of K2SO4 and CaSO4 2H2O produces large amounts waste water holding excess potassium sulfate. Therefore, this method is deemed ineffective, uneconomical environmentally unfriendly. Moreover, it crystals (ℓ ∼5-...

Herein, we report on the mechanochemical reaction of pyrrole and substituted benzaldehyde precursors to produce freebase corroles demonstrate one-pot synthesis 5,10,15-Tris(4-t-butylphenyl)corrole (H3t-buPhC), in which both, condensation oxidation reactions steps, took place ball mill. Moreover, could achieve copper with decent overall yields 10–12%. With approach shift EcoScale obtained from c...