نتایج جستجو برای: magnetic catalyst
تعداد نتایج: 381387 فیلتر نتایج به سال:
In this study, magnetic carbonaceous acids were synthesized by pyrolysis of the homogeneous mixtures of glucose and magnetic Fe3O4 nanoparticles, and subsequent sulfonation. The synthesis conditions were optimized to obtain a catalyst with both high acid density (0.75 mmol g(-1)) and strong magnetism [magnetic saturation, Ms = 19.5 Am(2) kg(-1)]. The screened catalyst (C-SO3H/Fe3O4) was used to...
The surface of magnetite nanoparticles as nano-sized solid support was modified with a molybdenum-Schiff base complex to prepare an easily separable heterogeneous catalyst for the epoxidation of olefins. Characterization techniques such as Fourier transform infrared and inductively coupled plasma optical emission spectroscopies, X-ray diffraction, vibrating sample magnetometry, scanning, an...
The acidic agent (SO3H) was stabilized on the silica coated Fe3O4 magnetic nanoparticles to produce Fe3O4@SiO2@Pr-SO3H, as a heterogeneous acidic catalyst, was designed, and then fully studied and characterized by FT-IR, XRD, TGA, DTA, TEM, and SEM analysis. Subsequently, the catalytic activity of Fe3O4...
In the present study, robust, versatile and straightforward strategy for the diversity-oriented convergent synthesis of a vast range of highly functionalized and biologically effective chromenes is introduced with the reaction of malononitrile, dimedone/cyclohexadione/4-hydroxycoumarin and benzaldehydes in the presence of [γ-Fe2O3@HAp-Si(CH2)3BF4@DMIM] as the catalyst. The structures of all the...
Magnetically separable photocatalyst beads containing nano-sized iron oxide in alginate polymer were prepared. This magnetic photocatalyst beads are used in slurry-type reactors. The magnetism of the catalyst arises from the nanostructured particles gamma-Fe(2)O(3), by which the catalyst can be easily recovered by the application of an external magnetic field. These synthesized beads are sunlig...
ni2+ supported on hydroxyapatite-core@shell γ-fe2o3 nanoparticles (γ-fe2o3@hap-ni2+) was found to be a useful catalyst for the synthesis of benzimidazole derivatives from o-phenylenediamine and aldehydes under solvent and solvent-free conditions at 80 °c. this reaction affords the corresponding benzimidazole derivatives compared with the classical reactions this method consistently gives a high...
n-propylsulfamic acid supported onto magnetic fe3o4 nanoparticles (mnps-psa) was investigated as an efficient and magnetically recoverable catalyst for the one-pot synthesis of substituted coumarins from the reaction of coumarin with variety aromatic aldehydes in high to excellent yield at room temperature under solvent-free conditions. the magnetic nanocatalyst can be readily recovered easily ...
ABSTRACT The functionalization of silica-coated Fe3O4 magnetic nanoparticles (Fe3O4@SiO2) using chlorosulfonic acid were afforded sulfonic acid-functionalized magnetic Fe3O4 nanoparticles (Fe3O4@SiO2-SO3H) that can be applied as an organic-inorganic hybrid heterogeneous catalyst. The used Fe3O4 magnetic nanoparticles are 18-30 nm sized that was rapidly functionalized and can be used as catalyst...
The development of new solid supports for palladium has received a lot of interest lately. These catalysts have been tested in a range of cross-coupling reactions, such as Suzuki–Miyaura, Mizoroki-Heck, and Sonogashira cross-coupling reactions, with good outcomes. Attaching the catalyst to a solid support simplifies the operations required in order to isolate and recycle the catalyst after a re...
the magnetic and recyclable nanoparticles of cofe2o4 were synthesized by a reverse co-precipitation process. sonication was used to couple the cofe2o4 surface with ag2o. the characteristics and optical properties of the catalyst were studied by powder x-ray diffraction, uv–visible reflectance spectroscopy and scanning electron microscopy analyses. pure cofe2o4 and cofe2o4/ag2o were utilized to ...
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