an anionic fe(ii) complex, (bmim)4[fe(cn)6] (where bmim is 1-butyl-3-methylimidazolium), was synthesized in ionic liquid [bmim][pf6] under reflux condition. the complex was characterized by elemental analysis and spectroscopic methods. the magnetite (fe3o4) nanoparticles were prepared by the hydrothermal and solvothermal (in ionic liquid [bmim][pf6]) methods from (bmim)4[fe(cn)6] as a precursor...

ABSTRACT The new PSP pincer ligand 4,6-bis(diphenylphosphinomethyl)dibenzothiophene (PSPPh) was prepared in 89 % yield. With this ligand, a solvothermal synthesis of a Cr complex of the type [Cr(κ3P,S,P-PSP)(CO)3] is described. The X-ray structure of this compound is presented. We demonstrate that the solvothermal synthesis technique provides a powerful, simple, and practical synthetic method r...

objective(s): according to the unique properties of magnetic nanoparticles, nickel metal-organic frameworks (mof) was synthesized successfully by ultrasound irradiation. metal-organic frameworks (mofs) are organic–inorganic hybrid extended networks that are constructed via covalent linkages between metal ions/metal clusters and organic ligands called a linker. materials and methods: the nanopar...

A method for the synthesis of 1,3-diarylpropylamines through hydroalkylation styrenes with benzylamines by potassium hydride has been developed. The protocol is initiated solvothermal treatment KH at 100 °C to generate deprotonated anionic species, which undergo selective C-alkylation arylalkenes 0 ambient temperature afford as major product.

Brominated flame retardants (BFRs) in electrical and electronic (E&E) waste plastic are toxic, bioaccumulative and recalcitrant. In the present study, tetrabromobisphenol A (TBBPA) contained in this type of plastic was tentatively subjected to solvothermal treatment so as to obtain bromine-free plastic. Methanol, ethanol and isopropanol were examined as solvents for solvothermal treatment and i...

This paper describes a reliable and sensitive method for sensing dissolved acetone using doped nanomaterials. Large-scale synthesis of ZnO nanorods (NRs) doped with Co3O4 was accomplished by a solvothermal method at low temperature. The doped NRs were characterized in terms of their morphological, structural, and optical properties by using field-emission scanning electron microscopy coupled wi...

W-doped TiO2 with nanoporous structure was synthesized by a one-step low temperature hydrothermal method using TiOSO4 and (NH4)6H2W12O40•xH2O as titanium and tungsten sources. Structure, morphology, specific surface area and chemical state of samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). W-doped nanoporo...

We report here the first example of ZIF materials synthesized in aqueous solution. The synthesis was performed at room temperature and typically took several minutes compared to hours and days in non-aqueous conditions. The obtained product were ZIF-8 nanocrystals having size of ~85 nm and showed excellent thermal, hydrothermal and solvothermal stabilities.