The SAFT-γ Mie group-contribution equation of state is used to represent the fluid-phase behavior aqueous solutions a variety linear, branched, and cyclic amines. New group interactions are developed in order model mixtures interest, including like unlike between alkyl primary, secondary, tertiary amine groups (NH2, NH, N), secondary (cNH, cN), methine-amine (cCHNH, cCHN) with water (H2O). grou...