_____________________________________________________________ Different catalysts based on Y-zeolite, ZSM-5 and amorphous kaolin were prepared and characterized. The catalytic cracking of 1,3,5-triisopropylbenzene (1,3,5-TIPB), 1,4diisopropylbenzene (1,4-DIPB) and n-dodecane were used to investigate the effect of catalyst nature on the catalytic performance. Cracking the largest molecule (1,3,5...

Electrochemical oxidation of some dyes making wastewater assisted by transition metal (Co, Cu) modified kaolin in an electrolytic cell with graphite plates as electrodes was investigated. H2O2, produced on the surface of porous graphite cathode reacts with the (Co, Cu) modified kaolin catalyst to form strong oxidant (hydroxyl radicals HO*) that can in turn degrade the pollutants adsorbed on the...

Caprolactam-based ionic liquids show many advantages, such as the lower toxicity, lower cost, and a simple preparation process. In this work, caprolactam-based ionic liquids were prepared and adopted as catalysts for the transesterification of Jatropha oil with methanol. The results demonstrated that the SO3H-functional caprolactam-based ionic liquids have higher catalytic activity than those o...

This work presents an efficient and selective enrichment method for glycoprotein/glycopeptides with sulfonic acid-functionalized mesoporous silica (SBA-15-SO3H), which is synthesized via simple oxidation of -SH groups with H2O2. The functionalized SBA-15 shows large surface area and accessible pores, and can selectively adsorb glycopeptides via hydrogen bond and hydrophilic interaction. Upon th...

Kaolin from the Buwambo deposit, located about 27 km north of Kampala (Uganda), has been analyzed for its mineralogical and chemical composition. The kaolin is derived from granite of the basement, which is exposed due to deeply weathered Buganda-Toro cover rocks. Kaolinite is the dominant mineral, with quartz and muscovite/illite as accessory minerals. Chemical data show that the kaolin is com...

BACKGROUND Although geophagia (earth eating) has been observed and documented in many areas of the world, the specific preference for consuming kaolin is less well known. The ingestion of kaolin, also known as white dirt, chalk, or white clay, is a relatively common type of pica found in the central Georgia Piedmont area. METHODS We reviewed the literature, made informal contacts with Georgia...

knoevenagel condensation between barbituric acid and aldehyde was investigated in the presence of sulfonic acid functionalized nanoporous silica (sba-pr-so3h) and resulted in the formation of arylidene and bis-arylidene barbiturates. excellent yields and short reaction times are related to the high efficiency of sba-pr-so3h that the reactions take place easily in its nano-pores. sba-pr-so3h as ...

a r t i c l e i n f o Keywords: Biodegradable polymer PHBHHx Kaolin Core–shell nanoparticle Nanocomposite A novel biodegradable nanocomposite was fabricated based on poly (3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) and silane-modified kaolinite/silica core–shell nanoparticles (SMKS), via solution-casting method using chloroform as solvent. Unmodified (ORK) and glycidoxypropyltrimethoxysi...

-Six well-characterized soil kaolins from widely separated sites in south-western Australia and four reference kaolins were studied by 57Fe M6ssbauer spectroscopy at room temperature after removal of non-structurally-bound iron with dithionite-citrate-bicarbonate solution. The soil kaolins and one of the reference kaolins were also studied at temperatures near 16 K. The soil kaolins were remark...

In bio-refinery and other catalytic reactions, heterogeneous catalysts confer advantage over homogenous due to minimized recovery separation costs. However, templating surfactant solid support for the synthesis of ought consider their cheap sources environmentally friendliness sustainable use. Thus, with vision make process significantly benign, in present work, acids were synthesised from rene...