Yamaguchi et al. have recently identified positions of hydrogen and deuterium atoms in photoactive yellow protein (PYP) using high-resolution neutron scattering. They reported that the hydrogen bond between the PYP chromophore and Glu46 was not a short ionic hydrogen bond (SIHB) but a low barrier hydrogen bond (LBHB). Furthermore, it was suggested that Arg52 close to the chromophore was deproto...

The orientational dynamics of water at a neutral surfactant reverse micelle interface are measured with ultrafast infrared spectroscopy of the hydroxyl stretch, and the results are compared to orientational relaxation of water interacting with an ionic interface. The comparison provides insights into the influence of a neutral vs. ionic interface on hydrogen bond dynamics. Measurements are made...

Introduction Sputter deposition technique provides extremely clean method to synthesize Au nanoparticles in ionic liquids without any stabilizing agents [1]. We have investigated the control factor for the size of Au nanoparticles prepared by this method. In this method, the length of alkyl chain of cation and the temperature of ionic liquids have a big role [2-4]. Especially, the temperature i...

The author has found recently that the lengths of chemical bonds are sums of the covalent and or ionic radii of the relevant atoms constituting the bonds, whether they are completely or partially covalent or ionic. This finding has been tested here for the skeletal bond lengths in the molecular constituents of nucleic acids, adenine, thymine, guanine, cytosine, uracil, ribose, deoxyribose and p...

Salts in the liquid phase at room temperature–ionic liquids– have recently received increased attention due to their unique properties.[1] These include high ionic conductivity, high thermal and chemical stability, broad electrochemical windows, non-volatility and non-flammability. These important properties make them versatile alternatives to conventional solvent-based systems, and their poten...