Water and air pollutants have huge impacts on the entire living system. In addition, the newly emerging nanopollutants, increasing global warming, and consequent climate changes are posing major threats to the freshwater or fresh air availability. This has made it urgent to invent an appropriate water/air treatment technology that removes nanopollutants and also desalinates water to a significa...

the effect of acetate ion introduced to aqueous solutions was investigated for the extraction/separation of ni and co from a dilute sulfate media. the separation of co and ni was improved by introducing acetate to aqueous media. by the use of the slope analysis method,the stoichiometric coefficient of the extractant was found to be 4 for cobalt and 3.5 or 4 for nickel depending on the acetate c...

Due to the proteomics revolution, multi-dimensional separation and detection instruments are required to evaluate many peptides and proteins in single samples. In this study, electrospray ionization (ESI) ion mobility spectrometry (IMS) was evaluated as an additional separation after HPLC separations. Common HPLC mobile phase compositions (solvents, acid modifiers, and buffers) were assessed fo...

The demonstration of the accumulation of citrate in vivo in the presence of fluoroacetate and the specific modification of this effect produced in various organs by the injection of malonate (14) have increased the desirability of isolation and quantitative determination of the acids of the Krebs cycle and related substances. Further, proposed studies involving the use of radioactive tracers re...

This manuscript presents our initial results and development of a novel hybrid instrument that combines atmospheric pressure ion mobility spectrometry (AP-IMS) with Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). Our preliminary results obtained from atmospheric pressure mobility separation of peptide mixtures combined with high-resolution FTICR mass analysis are demonst...

Heptanesulfonic acid as ion-pairing agent was used for the separation of mixtures of low and high molecular mass peptides/proteins by capillary electrophoresis. The separation conditions used were: capillary 37 cm (30 cm to the detector) x 75 microm i.d., voltage 10 kV, phosphate buffer 50 mmol/l, ion-pairing agent heptanesulfonic acid at three different concentrations, namely, 0, 20 or 100 mmo...

An electrospray ionization-dual gate-ion mobility-quadrupole ion trap mass spectrometer was used to evaluate the separation characteristics of isomeric flavonoid diglycosides adducted with sodium, potassium, and silver. This instrumental configuration allows ions to be selectively accumulated within the ion trap on the basis of their gas phase conformation prior to mass analysis. For the metal ...