The effect of molecular architecture of a surfactant, particularly the attachment position of benzene sulfonate on the hexadecane backbone, at the decane-water interface was investigated using atomistic MD simulations. We consider a series of surfactant isomers in the family of alkyl benzene sulfonates, denoted by m-C16, indicating a benzene sulfonate group attached to the mth carbon in a hexad...

We have used dynamic interfacial tension measurements to understand the structure of the ordered monolayer at the hexadecane/water interface induced by the presence of surfactant molecules. No abrupt changes in the interfacial tension (gamma) are observed during the expansion and contraction cycle below the interfacial ordering temperature (Ti) as observed for alkanes in contact with air. The l...

Immiscible polymers are often blended together to create new materials with desired properties. Knowledge of the interfacial tension between the immiscible polymers is important when designing such blending processes. Traditional methods of measuring the interfacial tension between low molecular weight fluids, e.g., the pendant or sessile drop method, the Wilhelmy balance, and the spinning drop...

Microbial enhanced oil recovery (MEOR) is a technology that could potentially increase the tertiary recovery of oil from mature oil formations. However, the efficacy of this technology in fractional-wet systems is unknown, and the mechanisms involved in oil mobilization therefore need further investigation. Our MEOR strategy consists of the injection of ex situ produced metabolic byproducts pro...

An investigation was conducted to study the reutilization of clear fracturing flowback fluids composed of viscoelastic surfactants (VES) with additives in surfactant flooding, making the process more efficient and cost-effective. The clear fracturing flowback fluids were used as surfactant flooding system with the addition of α-olefin sulfonate (AOS) for enhanced oil recovery (EOR). The interfa...

The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear Poisson-Boltzmann theory and compared with numerical results from nonlinear Poisson-Boltzmann theory. The excess liquid-liquid interfacial tension with respect...

The same relationship holds for the interfacial tension o-i at the consolute critical point (the critical point for phase separation) of a binary fluid mixture. Up to now no rigorous theory links the interfacial tension to properties of the bulk system. However, a phenomenological approach which should be valid in the vicinity of the critical point has been developed by Fisk and Widom. 2 Accord...

Chemical oil recovery from offshore reservoirs which are usually characterised by harsh conditions such as high salinities have remained a source of concern. This study assesses chemical compatibilities alkalis –surfactant systems under salinity and divalent ions (Ca2+ Mg2+). It analysed the synergy between alkali-surfactant slugs crude oil, leading to design an optimal low-cost alkaline- surfa...

Power transformers are one of the most significant and expensive equipment in power systems that exposed to electrical, thermal, chemical tensions. The transformer health index is a measure uses test data field inspections assess condition determine remaining life transformer. purpose this article as new idea relationships between physical, parameters oil, dissolved gases, index. One advantages...

Through this study, the ability of a modified Peng-Robinson (MPR) equation of state in predicting the surface tension of n-alkanes based on the density functional theory approach was investigated and compared with other studies. The interfacial layer thickness and the density profile were calculated simultaneously at different temperatures from triple point to near critical point using the modi...