appointment to the patient than this. During the early years of his career the eye-surgeon is also very disappointed with his results after this operation if lie takes the trouble to find out how small the amount of improvement is and he feels inclined to abandon the operation. The common causes of failure are : (1) Iris adherent to cornea. (2) Too small an iridectomy. (3) Extensive opacity of ...

Abstract The activation of C–H bonds is a central challenge in organic chemistry and usually key step for the retro-synthesis functional natural products due to high chemical stability bonds. Electrochemical methods are powerful alternative activation, but this approach requires overpotential homogeneous mediators. Here, we design electron-deficient W 2 C nanocrystal-based electrodes boost hete...

Fused filament fabrication is one of the most rapidly developing 3D printing techniques, with numerous applications, including in field applied electrochemistry. Here, utilisation conductive carbon black polylactic acid (CB-PLA) for printouts promising. To use CB-PLA as an electrode material, activation process must be performed, removing polymer matrix and uncovering electrically filler. We pr...

This paper describes the relationships between ultra-violet emission, ozone generation and CrVI production in MIG welding which were measured as a function of shield gas flow rate, welding voltage, electrode stick-out and shield gas composition using an automatic welding rig that permitted MIG welding under reproducible conditions. The experimental results are interpreted in terms of the physic...

In chemical analysis and electrochemical catalysis modified electrodes have been used in a wide range. In addition to the several methods of electrode modification reported in literature, the sol-gel route offers a possibility of preparing ceramic like films under rather mild conditions. This enhances the possibility of incorporation of temperature sensitive particles such as enzymes, microorga...

Novel graphite-molybdenum carbide nanocomposites (G-Mo2C) are synthesized by a typical solid state reaction with melamine and MoO3 as precursors under inert atmosphere. The characterization results indicate that G-Mo2C composites are composed of high crystallization and purity of Mo2C and few layers of graphite carbon. Mo2C nanoparticles with sizes ranging from 5 to 50 nm are uniformly supporte...

Many diseases are associated with oxidative stress, which occurs when the production of reactive oxygen species (ROS) overwhelms the scavenging ability of an organism. Here, we evaluated the carbon nanoparticle antioxidant properties of poly(ethylene glycolated) hydrophilic carbon clusters (PEG-HCCs) by electron paramagnetic resonance (EPR) spectroscopy, oxygen electrode, and spectrophotometric...

This work reports the development of a bienzyme system consisting of salicylate hydroxylase (SHL) and nitrate reductase (NaR) for the electrochemical determination of nitrate. This method measures the concentration of nitrate directly under ambient air without suffering from oxygen interferences. The determination is based on the detection of NADH consumption, and the principle is as follows: N...

A new strategy for preparing spatially-controlled, multi-component films consisting of molecular light absorbing chromophores and water oxidation catalysts on high surface area, mesoporous metal oxide surfaces is described. Atomic layer deposition (ALD) is used to embed a surface-bound chromophore in a thin layer of inert Al2O3, followed by catalyst binding to the new oxide surface. In a final ...