Volatile organic chemicals present at Superfund sites preferentially partition into the soil gas and may be available for microbial degradation. A simple mass transfer model for biodegradation for volatile substrates has been developed for the aerobic decomposition of aromatic and aliphatic hydrocarbons. The mass transfer analysis calculates diffusive fluxes from soil gas through water and memb...

background and objectives: analytical methods for volatile organic compounds (vocs) in different samples need extraction of compounds, by applying hazardous solvents. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which proper calibration can allow quantitative determinations of vocs at a very good sensitivity without the use of any organic solvent. vocs...

background: determination of organic pollutants usually requires extraction of the pollutants from samples, using hazard­ous solvent. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which, proper calibra­tion can allow quantitative measurements of organic pollutants at a very good sensitivity without the use of any organic sol­vent. because individual voc...

acetonitrile used as a solvent in manufactures and affects to central nervous system from inhalation exposure. the aim of this study was to develop a micro-solid phase extraction method for  the determination of acetonitrile in the air matrix. the sampling was performed with a small diameter fused silica fiber coated with a thin film of stationary phase and was subsequently desorbed and analyze...

[1] A unified tropospheric chemistry-aerosol model has been developed within the Goddard Institute for Space Studies general circulation model (GCM). The model includes a detailed simulation of tropospheric ozone-NOx-hydrocarbon chemistry as well as aerosols and aerosol precursors. Predicted aerosol species include sulfate, nitrate, ammonium, black carbon, primary organic carbon, and secondary ...

This paper considers the gas phase chemistry in a protoplanetary accretion disk, especially the chemistry initiated in the gas phase by destruction of dust close to the central star. Slow radial particle transport moves gas and dust from the cold outer parts of a protoplanetary accretion disk into its warm central part where chemical reactions in the gas phase are activated. At the same time ga...

biodegradation of petroleum hydrocarbons (20 g/kg dw soil) was investigated in 3 media, differing in the kind of petroleum fractions. in the laboratory experiments, during 5 months, the activities of petroleum hydrocarbon-degrading microorganisms and dehydrogenase activity of soil was determined. gas chromatographic analysis showed the biological decontaminations for gas oil, kerosene and synth...

Due to the large contribution of the coldstart process to unburned hydrocarbon emissions of an internal combustion engine during FTP cycle tests, we take a new look at the production of hydrocarbons inside the combustion chamber during coldstart. To this end a model is developed which predicts the exhaust port hydrocarbon concentration, exhaust gas temperature and equivalence ratio based on a s...

Secondary organic aerosol (SOA) formation from the reaction of isoprene with nitrate radicals (NO3) is investigated in the Caltech indoor chambers. Experiments are performed in the dark and under dry conditions (RH<10%) using N2O5 as a source of NO3 radicals. For an initial isoprene concentration of 18.4 to 101.6 ppb, the SOA yield (defined as the ratio of the mass of organic aerosol formed to ...