The deuterium isotope effect in the steady state CO oxidation rate over Au/ -Al2O3 in the presence of H2 or H2O and the effect of pretreatment on an uncalcined catalyst were studied. In a reaction feed containing 1% CO, 0.5% O2, and 40.5% H2 at room temperature, CO oxidation exhibited a deuterium isotope effect (kH/kD) of 1.4 ± 0.2. The rate of D2 oxidation was also slower than the oxidation of...

Molecular structures of 4-(((4-methoxyphenyl)amino)methyl)-N,N-dimethylaniline and 2-methoxy-5-((phenylamino)methyl)phenol synthesized via Schiff bases reduction route are reported. The compounds consist asymmetric units C16H20N2O (1) C14H15NO2 (2) in orthorhombic monoclinic crystal systems, respectively. Compound 1 intermolecular C11—H11···N2 hydrogen bonding with C11···N21 = 3.463(4) Å. hydro...

Analysis of available B-DNA type oligomeric crystal structures as well as protein-bound DNA fragments (solved using data with resolution <2.6 A) indicates that in both data sets, a majority of the (3'-Ade) H2..O2(3'-Thy/Cyt) distances in AA.TT and GA.TC dinucleotide steps, are considerably shorter than their values in a uniform fibre model, and are smaller than their optimum separation distance...

We report the measured total charge-transfer (electron-capture) cross sections for the ground state + 2 O (X Πg) ions with H2 and O2 molecular gases in the collision energy range between 0.50 and 2 keV. The time-of-flight technique has been used to measure the fast neutral products from + 2 O charge transfer reactions. The analyzed process has cross sections that continue to increase slowly, as...

This paper presents the simulations for a two-dimensional PEMFC with an interdigitated flow channel design using FEMLAB. The multi-species flow of O2, H2, H2O and inert N2 is examined over the entire fuel cell working range. The transportations of these gases in the porous anode/cathode are predicted using the Maxwell-Stefan transport equations and the Fick’s law; the flow field is predicted us...

Mixed matrix membranes (MMMs) are a strong alternative to the conventional polymeric which suffer from trade-off between selectivity and gas permeability. Considering existence of large number metal–organic frameworks (MOFs) polymers, computational screening MOF/polymer MMMs is strongly desired explore their upper limits in various separation processes before experimental efforts. In this work,...

Due to the higher hydrogen solubility and diffusivity, gadolinium sesquioxide (Gd2O3) could be expected as a proton conductive material. In this study, monoclinic Gd2O3 was used evaluate possible conductivity in Ar (?Ar), Ar+4% H2 (?H2), D2 (?D2), Ar+H2O (?H2O), Ar+D2O (?D2O), O2 (?O2) atmospheres temperature range from 500°C 1000°C, understand its application DT fuel system of nuclear fusion r...

Nanocomposites of tantalum-based pyrochlore nanoparticles and indium hydroxide were prepared by a hydrothermal process for UV-driven photocatalytic reactions including overall water splitting, hydrogen production from photoreforming of methanol, and CO2 reduction with water to produce CO. The best catalyst was more than 20 times more active than sodium tantalate in overall water splitting and 3...

The dual-pump coherent anti-Stokes Raman spectroscopy (CARS) method was used to measure temperature and the absolute mole fractions of N2, O2 and H2 in a supersonic non-reacting fuel-air mixing experiment. Experiments were conducted in NASA Langley Research Center’s Direct Connect Supersonic Combustion Test Facility. Under normal operation of this facility, hydrogen and air burn to increase the...

The high-quality graphene film can be grown on single-crystal Cu substrate by seamlessly stitching the aligned graphene domains. The roles of O2 and H2 have been intensively studied in the graphene growth kinetics, including lowering the nucleation sites and tailoring the domain structures. However, how the O2 and H2 influence Cu orientations during recrystallization prior to growing graphene, ...