A method for immobilizing protein crystals has been devised for determining face growth rates, and used to investigate the growth kinetics of hen egg white lysozyme crystals. Growth rates were determined at 22 degrees C in 0.1 M sodium acetate, 5% NaCl, pH 4.0, on the visually identified (110) face of tetragonal lysozyme crystals. Protein concentrations ranged from 13 to 57 mg/ml (saturation co...

The kinetics and mechanisms of graphene growth on Ni films at 720-880 °C have been measured using fast pulses of acetylene and real-time optical diagnostics. In situ UV-Raman spectroscopy was used to unambiguously detect isothermal graphene growth at high temperatures, measure the growth kinetics with ∼1 s temporal resolution, and estimate the fractional precipitation upon cooldown. Optical ref...

experiments were carried out in which the dependence of the fractional softening on temperature, time and strain rate was determined in a 304h stainless steel. three prestrain ranges were identified pertaining to three different post-deformation softening behaviors: 1) prestraining to below the drx critical strain: strongly strain dependent softening by srx alone with softening kinetics control...

The initial growth kinetics for SiH, chemical vapor deposition of Si on SiO, at low temperature (500-600 “C) have been revealed using rapid thermal UHV-CVD, together with in situ H2 thermal desorption spectroscopy to titrate the amount of exposed Si surface. In the few mTorr pressure range, the reaction is heterogeneous, i.e., dominated by surface reaction. Below -0.7 monolayer Si coverage, the...

A moving, solidifying interface that grows by the instantaneous adsorption of a diffusing solute can be described by equations analogous to those of the classical one-sided Stefan problem for solidification. However, the behavior of precipitate growth by material deposition can depend on both surface kinetics and bulk drift of the depositing species. We generalize the Stefan problem and its int...

Microbial growth on and utilization of environmental contaminants as substrates have been studied by many researchers. Most times, substrate utilization results in removal of chemical contaminant, increase in microbial biomass and subsequent biodegradation of the contaminant. These are all aimed at detoxification of the environmental pollutants. Several microbial growth and biodegradation kinet...

The crystallisation of struvite is one means of removing phosphate (and nitrogen) from nutrient-rich wastewater. As with all crystallisation processes, the growth rate of the crystals and its dependence on supersaturation is of considerable interest in designing processing equipment. Modelling of struvite solubility using the computer package MINTEQA2 showed that struvite exhibits a minimum sol...

â  abstract: in this work, the kinetics of ethane hydrate formation has been studied experimentally and a kinetic model based on chemical affinity has been described for predicting the hydrate growth process in the stirred batch reactor at a constant volume. the experiments were done with both pure water and aqueous solution of sodium dodecyl sulfate (sds). the effect of sds on formation kineti...