In intensive agricultural systems runoff is one of the major potential diffuse pollution pathways for pesticides and poses a risk to surface water. Ditches are common in the Po Valley and can potentially provide runoff mitigation for the protection of watercourses. The effectiveness depends on ditch characteristics, so there is an urgent need for site-specific field trials. The use of a fugacit...

Hydrogen concentration gradients reported in olivines from several peridotite xenoliths (Demouchy, 2004; Peslier and Luhr, 2006) have been interpreted as evidence of hydrogen loss during ascent to the surface. However, a review of hydrogen diffusion data in anhydrous minerals (Ingrin and Blanchard, 2006) provides new constraints on the possible origin of these heterogeneities. The amount of hyd...

Siderophile elements are depleted in the Earth's mantle, relative to chondritic meteorites, as a result of equilibration with core-forming Fe-rich metal. Measurements of metal-silicate partition coefficients show that mantle depletions of slightly siderophile elements (e.g. Cr, V) must have occurred at more reducing conditions than those inferred from the current mantle FeO content. This implie...

A fugacity approach was evaluated to reconcile loadings of vinyl chloride (chloroethene), benzene, 1,3-butadiene and trichloroethylene in waste with concentrations observed in landfill gas monitoring studies. An evaluative environment derived from fictitious but realistic properties such as volume, composition, and temperature, constructed with data from the Brogborough landfill (UK) test cells...

Introduction: The partitioning of oxygen between silicates and liquid Fe-rich metallic alloy is a key factor in controlling chemical differentiation during core formation in terrestrial planets [1]. This is because oxygen partitioning determines the oxygen fugacity uniquely for a given bulk composition and therefore controls the partitioning of Fe and other siderophile elements during core form...