It is a great pleasure to be able to introduce this Themed series on organo-fluorine chemistry in the Beilstein Journal of Organic Chemistry. The introduction of fluorine into organic molecules is widely practiced particularly when tuning the properties of molecules for specialist functions. Of particular prominence is the role fluorine substitution finds in pharmaceutical development [1], and ...

The aims of this study were to evaluate the fluorine depth profiles of pure titanium (Ti), stainless steel (SUS), and polymethyl methacrylate (PMMA) modified by plasma-based fluorine ion implantation and the effects of fluorine ion implantation on contact angle, fluoride ion release, and S. mutans adhesion. Fluorine-based gases used were Ar+F2 and CF4. By means of SIMS, it was found that the pe...

We report density functional electronic structure calculations to monitor the change in the surface characteristics of the Si (100)-2x1 surface after fluorination followed by interaction with water. Embedded finite silicon clusters are used to model an extended Si (100)-2x1 surface. Two high symmetry pathways and subsequent adsorption sites were examined: (i) adsorption of an fluorine atom dire...

Neutral fluorine (F i) lines are identified in the optical spectra of several RCoronae Borealis stars (RCBs) at maximum light. These lines provide the first measurement of the fluorine abundance in these stars. Fluorine is enriched in some RCBs by factors of 800 to 8000 relative to its likely initial abundance. The overabundances of fluorine are evidence for the synthesis of fluorine. These res...

As a functional decorative material on the surface of printing and packaging, coating plays role increasing gloss, wear resistance, antifouling. It has broad application prospects in high-end printed materials such as posters, art reproductions, maps. In this paper, dodecafluoroheptyl methacrylate was used fluorine-containing monomer, which to modify epoxy resin introduce fluoride first. Under ...

The results of the study of the impact of phosphogypsum on the accumulation and migration of fluorine in the southern chernozems of the North-West Black Sea coast area of Ukraine are presented herein. It has been found that the introduction of phosphogypsum as a chemical ameliorator of irrigated chernozems resulted in a fluorine increase both in the soils and in the soil (lysimetric) waters.1 D...

Chromium-vanadium (Cr-V) bimetallic catalysts are prepared by the introduction of vanadium into the Phillips catalyst which is one of the most significant industrial ethylene polymerization catalysts for tuning the Phillips catalyst performances and improving polyethylene properties. In the present work, titanium species were introduced into the fluorine-modified chromium-vanadium bimetallic ca...

The purpose of the present study was to examine the effectiveness of fluorine and silver ions implanted and deposited into acrylic resin (poly(methyl methacrylate)) using a hybrid process of plasma-based ion implantation and deposition. The surface characteristics were evaluated by X-ray photoelectron spectroscopy (XPS), contact angle measurements, and atomic force microscopy. In addition, an a...

the effects of halogens; fluorine, chlorine and bromine, on the stability and multiplicity of phenylcarbenes / silylenes/ germylenes structures are compared and contrasted at b3lyp/6-311++g**//b3lyp/6-31+g* level. the singlet-triplet energy gaps, δes-t , values for all the above speciesincrease through fluorinated up, δes-ts and δehomo–lumos support the stability of the singlet statesinspite of...

The separation of both emulsified and immiscible oil/water mixtures using materials with special wetting behavior (hydrophobic-oleophilic or hydrophilic-oleophobic switchable wettability) has attracted significant research attention in recent years. Among various behavior, waste material-mediated surfaces have gained more interest because their advantages such as fluorine-free specific surface ...