The first examples of layered hybrid iron fluorides are reported. In the reactions carried out, chain compound (H2pipz)FeF5·H2O always occurs as major phase, with compounds, (H2pipz)3Fe4F18·2H2O and (H2pipz)2Fe3F13·H2O, being isolated from some impurities. latter two compounds feature two-dimensional sheets corner-and edge-shared FeIIIF6 octahedra, resulting in distinct layer architectures. (H2...

A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et(3)N·3HF reagent to provide branched allylic fluorides with complete regioselectivity. This high-yielding reaction can be conducted on a multigram scale and shows considerable functional gr...

statement of the problem generally, the main source of fluoride intake is drinking water. excessive consumption of bottled water as a substitute or in addition to the tap water supply may have implications for safe fluoride supplementation. in this study, fluoride contents in six commercial brands of bottled water were measured materials and methods six different brands of bottled drinking wate...

objectives: this study aimed to assess the self-reported knowledge and attitude of dentists towards fluoride prescription. materials and methods: a questionnaire survey was conducted at the national annual dental congress in 2010 in tehran-iran. dentists’ level of knowledge about the preventive effects of systemic and topical administration of fluoride was assessed as well as their attitudes to...

We demonstrate a novel approach for the large-scale, shape-controlled synthesis of one-dimensional (1D) corrugated nanoarrays of Pb(1-x)Mn(x)Se nanocrystals (0.002 < or = x < or = 0.008) through an in-situ self-assembly without using either capping polymer or ionic surfactant. The one-step-prepared 1D nanoarrays exhibit a well-defined morphology, single-crystal orientation, and clean surface wi...

We have developed a new green chemical approach for the shape-controlled synthesis of single-crystalline hematite nanocrystals in aqueous medium. FESEM, HRTEM and SAED techniques were used to determine the morphology and crystallographic orientations of each nanocrystal and its exposed facets. PXRD and HRTEM techniques revealed that the nanocrystals are single crystalline in nature; twins and s...

A rice starch based film, reinforced with starch nanocrystals (prepared by submitting native granules of rice starch to acid hydrolysis at 40 oC) was prepared by casting film-solution on leveled trays. The influence of the content of starch nanocrystals (5 to 30%) on the mechanical, thermal and structural properties of rice starch films was investigated. The rice starch films showed an increase...

Trapped as molecular solids, the transition metal fluorides ZnF(2) and MeZnF-the latter isolated for the first time-exist as adducts in [(Cp*TiF(3))(8)(ZnF(2))(3)] (1) and [(Cp*TiF(3))(4)(MeZnF)(2)] (2), respectively. Compounds 1 and 2 were obtained in reactions of [Cp*TiF(3)] (Cp*=C(5)Me(5)) with ZnMe(2) and Me(3)SnF in various molar ratios. The single-crystal structure of 1 is shown here; the...

We review the room temperature optical and electronic properties of single semiconductor nanocrystals, which are made by chemical synthesis. Confocal luminescence spectroscopy of single nanocrystals reveals a blinking behavior apparently due to an intermittent photoionization. To investigate this further, the dielectric constant and electrostatic charge of single CdSe nanocrystals was measured....

Background The aim of this study was to prepare and evaluate the impact of polymers on fabricating stable dexibuprofen (Dexi) nanocrystals with enhanced therapeutic potential, using a low energy, anti-solvent precipitation method coupled with molecular modelling approach. Methods Dexi nanocrystals were prepared using antisolvent precipitation with syringe pump. Crystallinity of the processed ...