Excited-state trajectories computed at the complete active space second-order perturbation theory (CASPT2) reveal how vibrational excitation controls the molecular approach to the intersection space that drives the photodissociation of a prototypical halogenated methyl radical, namely CF2I. Translating the Franck-Condon structure along the ground-state CASPT2 vibrational modes in this system fo...

We consider a two-dimensional pulse-coupled array of noisy threshold elements with a long-range interaction. For tight coupling, we observe the formation of spatio-temporal excitation waves, such as target and spiral waves. For weak coupling, we find noise sustained spiral growth, where the noise level controls the scale of the spiral. (c) 1995 American Institute of Physics.

We demonstrate |W⟩ state encoding of multiatom ensemble qubits. Using optically trapped Rb atoms, the T_{2} coherence time is 2.6(3) ms for N[over ¯]=7.6 atoms and scales approximately inversely with the number of atoms. Strong Rydberg blockade between two ensemble qubits is demonstrated with a fidelity of 0.89(1), and with a fidelity of ∼1.0 when postselected on a control ensemble excitation. ...

Entanglement is at the heart of quantum technologies such as quantum information and quantum metrology. Providing larger quantum Fisher information (QFI), entangled systems can be better resources than separable systems in quantum metrology. However the effects on the entanglement dynamics such as decoherence usually decrease the QFI considerably. On the other hand, Dzyaloshinskii-Moriya (DM) i...

The construction of Green's tensor for two-dimensional gyrotropic photonic clusters composed of cylinders with circular cross sections using the semi-analytic multipole method is presented. The high efficiency and accuracy of the method is demonstrated. The developed method is applied to gyrotropic clusters that support topological chiral Hall edge states. The remarkable tolerance of chiral Hal...

We show that extra resonances, such as those caused in frequency-domain nonlinear wave mixing by pure dephasing or laser fluctuations, can also be induced by operation in the time domain. These pulse-length-induced extra resonances arise in transient-grating experiments when the laser pulses are short enough that a steady state cannot be achieved during the excitation process. We show theoretic...

We propose and experimentally demonstrate the method of population transfer by piecewise adiabatic passage between two quantum states. Coherent excitation of a two-level system with a train of ultrashort laser pulses is shown to reproduce the effect of an adiabatic passage, conventionally achieved with a single frequency-chirped pulse. By properly adjusting the amplitudes and phases of the puls...

We demonstrate nonlinear excitation of surface plasmons on a gold film by optical four-wave mixing. Two excitation beams of frequencies omega(1) and omega(2) are used in a modified Kretschmann configuration to induce a nonlinear polarization at a frequency of omega(4wm)=2omega(1)-omega(2), which gives rise to surface plasmon excitation at a frequency of omega(4wm). We observe a characteristic p...