Degradation of 2,4-dichlorophenol (2,4-DCP) was studied in a novel three-electrode photoelectrocatalytic (PEC) integrative oxidation process, and the factors influencing the degradation rate, such as applied current, flow speed of O2, pH, adscititious voltage and initial 2,4-DCP concentration were investigated and optimized. H2O2 was produced nearby cathode and Fe2+ continuously generated from ...

2,4-dichlorophenoxyacetic acid (2,4-D) is a widely used herbicide for controlling broad-leaved weeds. The development of an efficient process treating the refractory 2,4-D wastewater necessary. In this study, liquid-phase degradation induced by radio frequency discharge (RFD) was studied. Experimental results showed that more effective in acidic than neutral or alkaline solutions. During degrad...

Currently, the textile industry is one of the most important economic sectors in many countries. Besides, it is known as a major consumer of water and consequently one of the largest groups of industries causing intense water pollution. Chemicals, including surfactants, dyes, resins, dispersants agents, inorganic salts, etc., play a variety of functions during the textile processing and are pre...

Acceleration of the autoxidation of Fe2+ by apotransferrin or apolactoferrin at acid pH is indicated by the disappearance of Fe2+, the uptake of oxygen, and the binding of iron to transferrin or lactoferrin. The product(s) formed oxidize iodide to an iodinating species and are bactericidal to Escherichia coli. Toxicity to E. coli by FeSO4 (10(-5) M) and human apotransferrin (100 micrograms/ml) ...

The Fenton reaction as an effective advanced oxidation technology has been widely used in wastewater treatment for its stable effluent quality, simple operation, mild condition, and higher organic degradation with non-selectivity. However, the traditional is limited by sluggish regeneration of Fe2+, resulting a slower rate, it necessary to further increase dosage which will production iron slud...

The combination of surfactant enhanced soil washing and degradation of nitrobenzene (NB) in effluent with persulfate was investigated to remediate NB contaminated soil. Aqueous solution of sodium dodecylbenzenesulfonate (SDBS, 24.0 mmol L-1) was used at a given mass ratio of solution to soil (20:1) to extract NB contaminated soil (47.3 mg kg-1), resulting in NB desorption removal efficient of 7...

Oxidizing agents are powerful activators of factors responsible for the transcriptional activation of cytokine-encoding genes involved in tissue injury. In this study we show evidence that STAT3 is a transcription factor whose activity is modulated by H2O2 in human lymphocytes, in which endogenous catalase had previously been inhibited. H2O2-induced nuclear translocation of STAT3 to form sequen...

Deferoxamine accelerates the autooxidation of iron as measured by the rapid disappearance of Fe2+, the associated appearance of Fe3+, and the uptake of oxygen. Protons are released in the reaction. The formation of H2O2 was detected by the horseradish peroxidase-catalyzed oxidation of scopoletin, and the formation of hydroxyl radicals (OH.) was suggested by the formation of the OH. spin trap ad...

Consideration of the changes in free energy shows that assumed initial steps reactions H2O2 with Fe2+ and Fe3+ radical theory are not consistent. The is unable to account for Fe3+-initiated decomposition or oxidations by it. In ions at high [H2O2], where O2 evolution reaches a limit, such limit foreseen model. At lower because disallowed substitution equation used, interpretation valid. It appe...

aims: in biological wastewater treatment processes, a large amount of sludge is produced. stabilization of sludge is essential before disposal because of the risks to human health and environment. therefore, selecting an appropriate process for stabilization this sludge may efficiently decrease risks. the aim of this study was to examine the compound efficiency of the advanced fenton and ozonat...