the nanocrystallization of co67fe4cr7si8b14 amorphous ribbons which prepared by planar flow melt spinning process (pfms) was investigated. crystallization of the ribbons was studied by differential thermal analysis (dta), x-ray diffraction (xrd) and transmission electron microscopy (tem). the dta result of amorphous ribbon at heating rate of 10˚c/min showedoccurrence of phase transitions in two...

Electrochemical impendence spectroscopy (EIS), cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were performed to investigate the barrier properties and electron transfer of derivatized thiol self-assembled monolayers (SAMs) on gold in the presence of surfactants. The thiol derivatives used included 2-mercaptoethanesulfonic acid (MES), 2-mercaptoacetic acid (MAA), and N-acetyl-L...

We report on the fundamental electrochemical properties of inherently hydrophobic Multiwalled Carbon Nanotubes MWNT electrodes and acid treated MWNTs. The electrochemical response of the electrodes was investigated by cyclic voltammetry and ac impedance spectroscopy using the redox probe of (Fe(CN)6 /Fe(CN)6 , which has well-known kinetic behaviour on carbon surfaces. Comparisons were made betw...

In this study, the effect of molybdate on the electrochemical behavior and semi-conductive properties of duplex stainless steel 2205 passive film at NaCl solutions was investigated. Cyclic potentiodynamic polarization, impedance spectroscopy, mott-schottky plots and scanning electron microscopy (SEM) were used to study the passive behavior. Polarization curves showed that the corrosion current ...

In an effort to develop new ruthenium(II) complexes, this work describes the design, synthesis and characterization of a ruthenium(II) functionalized phenanthroline complex with extended π-conjugation. The ligand were L(1) (4,7-bis(2,3-dimethylacrylic acid)-1,10-phenanthroline), synthesized by a direct aromatic substitution reaction, and L(2) (4,7-bis(trianthracenyl-2,3-dimethylacrylic acid)-1,...

copper vanadate nanostructures were prepared via ex-situ precipitation approach in presence of schiff-base ligand (n,n׳ -buthylenebis(acetylacetone iminato)dianion = acacbn) as a new capping agent. the effect of different cu sources and ph on the size, morphology and size distribution of copper vanadate nanostructures was investigated. the as-prepared products were characterized using x-ray dif...