On July 4, 2014, the Office of Environmental Health Hazard Assessment (OEHHA) released the draft document, Methylene Diphenyl Diisocyanate Reference Exposure Levels: Technical Support Document for the Derivation of Noncancer Reference Exposure Levels to solicit public comment. Responses to comments received on the draft methylene diphenyl diisocyanate reference exposure levels (RELs) are provid...

In the title compound, C(19)H(17)ClNO(3)P, the P atom exhibits a distorted tetra-hedral configuration. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form centrosymmetric dimers.

The N-H bond in the title compound, C(13)H(14)NO(3)P, is syn-oriented relative to the P=O bond. The N atom deviates somewhat from planarity, the sum of the bond angles being 353.3°. The P atom has a distorted tetra-hedral coordination; its bond angles are in the range 93.96 (5)-116.83 (6)°. In the crystal, mol-ecules form centrosymmetric dimers through P=O⋯H-N hydrogen bonds.

In the title mol-ecule, C(17)H(20)NO(3)P, the P atom is bonded in a distorted tetra-hedral environment. The dihedral angle between the two phenyl rings is 23.52 (10)°. The phosphoryl and N-H groups are anti with respect to one another. The -CH(2)-CH(2)-CH(2)-CH(2)- sequence of atoms in the cyclo-pentyl ring is disordered over two sets of sites with refined occupancies of 0.574 (10) and 0.426 (1...

This paper selects two typical compounds containing organic sulfur as model compounds. Then, by analyzing the chromatograms of gaseous low-temp oxidation products and GC/MS of the extractable matter of the oxidation residue, we summarizing the mechanism of low-temp sulfur model compound oxidation. The results show that between 30°C to 80°C, the interaction between diphenyl sulfide and oxygen is...