نتایج جستجو برای: dimethyl sulfoxide dmso

تعداد نتایج: 29583  

Journal: :The journal of physical chemistry. B 2010
Xiangke Chen Babak Minofar Pavel Jungwirth Heather C Allen

The molecular organization at the aqueous dimethyl sulfoxide (DMSO) and methanesulfonic acid (MSA) surfaces was investigated using vibrational sum frequency generation (VSFG) spectroscopy and molecular dynamics (MD) simulation. The molecular orientation of surface DMSO and MSA is deduced based on the VSFG spectra of both C-H stretch and S-O stretch regions. The S-O stretch region was studied fo...

Journal: :Journal of biomedical optics 2013
Ping Liu Yanyue Huang Zhouyi Guo Jianping Wang Zhengfei Zhuang Songhao Liu

Confocal micro-Raman spectroscopy is employed to study the diffusion process of dimethyl sulfoxide (DMSO) in porcine skin optical clearing. The variation of DMSO concentration with time at different depths of the skin was obtained and then the DMSO diffusion coefficient with the passive diffusion model was calculated. Results show that it has a significant difference at different depths of the ...

Journal: :Environmental science & technology 2016
Shinichi Enami Yosuke Sakamoto Keiichiro Hara Kazuo Osada Michael R Hoffmann Agustín J Colussi

The oxidation of biogenic dimethyl sulfide (DMS) emissions is a global source of cloud condensation nuclei. The amounts of the nucleating H2SO4(g) species produced in such process, however, remain uncertain. Hydrophobic DMS is mostly oxidized in the gas phase into H2SO4(g) + DMSO(g) (dimethyl sulfoxide), whereas water-soluble DMSO is oxidized into H2SO4(g) in the gas phase and into SO4(2-) + Me...

2017
Chen Liu Ashley C Felts Daisuke Takahashi Wesley S Kinden Khalil A Abboud

In the title complex, [Ni(C7H3NO4)(C2H6OS)2(H2O)], the NiII cation is situated on a twofold rotation axis and exhibits a distorted octa-hedral NO5 coordination environment defined by a tridentate pyridine-2,6-di-carb-oxy-lic acid dianion (dpa2-), two dimethyl sulfoxide (DMSO) mol-ecules, and a water mol-ecule. In the crystal, the complex mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds i...

2012
Ismail Warad Abdullah S. Aldwayyan Fahad M. Al-Jekhedab M. Iqbal Choudhary Sammer Yousuf

In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl-ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol-ecule are disordered over two sets of sites in a 0.8976 (18):0.1024 (18) ra...

2008
Kong Wai Tan Chew Hee Ng Mohd Jamil Maah Seik Weng Ng

The Zn(II) atom in the title compound, [Zn(C(8)H(7)N(3)O(2)S)(C(12)H(8)N(2))]·2C(2)H(6)OS·H(2)O, is N,N'-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear mol-ecule, the water and the dimethyl sulfoxide (DMSO) mol-ecules into a linear chain motif. One DMSO mol-ecule is disordered over ...

2011
Fu-Lin Zhou Zhi-Hua Du Seik Weng Ng

The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro-benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti-prismatic environment. There are two independent formula units in the asymmetric unit. The S ato...

2016
Eduard Chygorin Yuri Smal Irina V. Omelchenko

The title compound, [Fe3(C11H11N2O5)2Cl3(C2H6OS)3]2·7C2H6OS·2H2O, was isolated accidentally from an Fe0-NiCl2·6H2O-H3L-TEA-DMSO system [where H3L is the product of the condensation between p-nitro-salicyl-aldehyde and 2-amino-2-methyl-propane-1,3-diol and dimethyl sulfoxide (DMSO), and TEA is triethylamine]. The structure is based on a trinuclear {Fe3(μ-O)4} core, with an angular arrangement of...

Journal: :Biogeosciences 2021

Abstract. Dimethyl sulfide (DMS), dimethylsulfoniopropionate (DMSP) and dimethyl sulfoxide (DMSO) were measured at the Boknis Eck Time Series Station (BE, Eckernförde Bay, SW Baltic Sea) during period February 2009–December 2018. Our results show considerable interannual seasonal variabilities in mixed-layer concentrations of DMS, total DMSP (DMSPt) DMSO (DMSOt). Positive correlations found bet...

2016
Narjes Soltani Elham Mohammadi Mohammad Allahtavakoli Ali Shamsizadeh Ali Roohbakhsh Abbas Haghparast

INTRODUCTION Dimethyl sulfoxide (DMSO) is a chemical often used as a solvent for water-insoluble drugs. In this study, we evaluated the effect of intracerebroventricular (ICV) administration of DMSO on neural response characteristics (in 1200-1500 μm depth) of the rat barrel cortex. METHODS DMSO solution was prepared in 10% v/v concentration and injected into the lateral ventricle of rats. Ne...

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