BACKGROUND Hexavalent chromium (Cr(VI)) is a common environmental pollutant. Cr(VI) exposure can lead to severe damage in the liver, but the preventive measures to diminish Cr(VI)-induced hepatotoxicity need further study. Acid sphingomyelinase (ASMase) is responsible for the production of ceramide via the hydrolysis of sphingomyelin. The present study was designed to investigate effects of des...

Strong anion exchange resin (Spectra/Gel IE 1x8) has been investigated as adsorbent for the efficient removal of Cr(VI) ions from synthetic wastewater solutions. Batch experiments were conducted with initial Cr(VI) ions concentration ranging from 25-300 mg/L. Different parameters influencing Cr(VI) adsorption process such as; solution pH, Cr(VI) and adsorbent concentration and contact time were...

The wood preservative chromated copper arsenate (CCA) contains hexavalent chromium [Cr(VI)] and the conversion of Cr(VI) to trivalent chromium [Cr(III)] drives fixation of the treatment chemicals to the wood fibers. Since the toxicity of Cr depends on its valence state, an assessment of the Cr species occurring in CCA-treated wood, as well as leachates and ashes from CCA-treated wood, is helpfu...

Using ground granulated blast-furnace slag (GGBS) under different alkaline conditions, we studied the mechanisms and extents of Cr(VI) reduction and sorption and compared them to reactions with Portland cement (PC). We also investigated the effects of mixing PC/GGBS ratios on Cr(VI) dissolution after carbonating the substrates. We observed a complete sorption and reduction of Cr(VI) to Cr(III) ...

A simple method using solid-phase extraction combined with metal furnace atomic absorption spectrometry was developed for the determination of Cr(III) and Cr(VI) at sub-ppb levels in water. A 500-ml water sample was adjusted to pH 3 with nitric acid and then passed through an iminodiacetate extraction disk placed on a cation-exchange extraction disk at a flow rate of 20-40 ml min(-1) for concen...

A new method involving pre-concentration on modified silica fiber is described for the speciation of chromium(III) [Cr(III)] and chromium(VI) [Cr(VI)] in aqueous media. This method is based on the different chelating behavior of Cr(III) and Cr(VI) with morpholine-4-carbodithioate (MDTC). Both complexes are extracted on silica fiber modified by sol-gel technology by using 3-aminopropyltriethoxys...

Cr(VI) is a highly toxic metal ion and considered a priority pollutant released from various chemical industries. Treatment methods to remove Cr(VI) from water and wastewater include chemical precipitation, ion exchange, membrane separation, electro-coagulation and reduction. These methods are not economically viable for large scale treatment of wastewater that is rich in Cr(VI). Adsorption is ...

A chromate-removing strain was isolated from spent chrome effluent and identified as Bacillus circulans strain MN1. The isolated strain was studied for resistance to Cr (VI) and its ability to remove Cr (VI). The strain was found to tolerate Cr (VI) concentration as high as 4500 mg/L, but the cells growth was heavily influenced when initial Cr (VI) concentration was increased between 1110 mg/L ...

A hybrid adsorbent (FOAE) prepared by loading ferric oxyhydroxide on anion exchanger was applied for adsorptive removal of Cr(VI) from water. Effects of initial Cr(VI) concentration, pH, temperature and competition of other anions on Cr(VI) adsorption were investigated in batch experiments. The equilibrium adsorption capacity (Qe) of the FOAE increased with initial Cr(VI) concentrations (from 2...

background: the presence of heavy metals in the environment especially in water supplies have caused many concerns because of their toxicity and non-degradability. hexavalent chromium (cr) is one of the most toxic metals which is used in many industries, so it is essential to remove it from industrial wastewater. in this study, we made a comparison between different adsorption isotherms in the ...