Abstract Linear polyhydromethylsiloxane (PHMS) was functionalized with nitrogen-containing organic compounds: N -allylaniline (Naa), -allylcyclohexylamine (Nach), -allylpiperidine (Nap) and 4-vinylpyridine (4VP) via hydrosilylation reaction in the presence of Pt 0 complex (Karstedt’s catalyst) under mild conditions. Reaction course followed by FTIR spectroscopy final products were characterized...