Mechanochemically responsive (MCR) polymers have been synthesized by incorporating mechanophores – molecules whose chemical reactions are triggered by mechanical force – into conventional polymer networks. Deformation of the MCR polymers applies force on the mechanophores and triggers their reactions, which manifest as phenomena such as changing colors, varying fluorescence and releasing molecu...

The effect of carbon black on the mechanical properties of elastomers is of great interest, because the filler is one of principal ingredients for the manufacturing of rubber products. While fillers can be used to enhance the properties of elastomers, including stress-free swelling resistance in solvent, it is widely known that the introduction of fillers yields significant inelastic responses ...

The objective of this study was to investigate the effect of fluoridated elastomeric ligatures on the microbiology of local dental plaque in vivo. This randomized, prospective, longitudinal, clinical trial had a split-mouth crossover design. The subjects were 30 patients at the beginning of their treatment with fixed orthodontic appliances in the orthodontic departments of the Liverpool and the...

background: there have been numerous researches on elastomeric ligatures, but clinical conditions in different stages of treatment are not exactly similar to laboratory conditions. the aim of this in vitro study was to simulate clinical conditions and evaluate the effect of three stretching patterns on the amount of force, tensile strength (ts) and extension to ts of the elastomers during 8 wee...

The purpose of the study was to investigate the biocompatibility of experimental elastomers, E580 and E590. The experimental elastomers and the control--a clinically used elastomer--were implanted into the subcutaneous tissue of rats. The tissue reactions were examined histologically on the 3rd, 7th, 14th, 28th, and 56th day after implantation. It was found that there were some irritant respons...

Nematic elastomers exhibit a rich elastic response to external stresses. Of particular interest is the semisoft response of elastomers with an anisotropy direction (z) frozen in by a double cross-linking process. This response is characterized by a stress-strain curve for stresses along x perpendicular to z that rises initially, exhibits a nearly flat plateau between two critical values of stra...

At the A to C transition, smectic elastomers have recently been observed to undergo approximately 35% spontaneous shear strains. We first explicitly describe how strains of up to twice this value could be mechanically or electrically induced in Sm-C elastomers by rotation of the director on a cone around the layer normal with an elastic cost dependent on constraints. Second, for typical sample ...

Recent advances in the cataloguing of three-dimensional nets mean a systematic search for framework structures with specific properties is now feasible. Theoretical arguments about the elastic deformation of frameworks suggest characteristics of mechanically isotropic networks. We explore these concepts on both isotropic and anisotropic networks by manufacturing porous elastomers with three dif...

Synthetic biodegradable elastomers are an emerging class of materials with many potential clinical applications including drug delivery and tissue engineering. Biodegradable elastomers offer advantages of structure diversity, tunable properties, and a wide range of processing capabilities. This review highlights some recent developments in various aspects of biodegradable materials synthesis, c...

Smectic elastomers [1] are rubbery materials that have the macroscopic symmetry properties of smectic liquid crystals [2]. They are sure to have intriguing properties, some of which have already been studied experimentally and/or theoretically [1]. Very recently, seminal progress has been made on smectic-C (SmC) elastomers forming spontaneously from a smectic-A (SmA) phase upon cooling. Hiraoka...