|The construction of a ame dictionary of ame speeds and preheat thicknesses for a given reaction will be discussed. Once the entries of the dictionary have been established, they can be accessed by researchers and programmers to be used in diierent combustion applications. An application of the ame dictionary for turbulent combustion in a circular cylinder is given. Chemical reactions are often...

A reduced primary reference fuel (PRF)-alcohol-di-tert-butyl peroxide (DTBP) mechanism with 108 species and 435 reactions, including sub-mechanisms of PRF, methanol, ethanol, DTBP, and the four butanol isomers, is proposed for homogeneous charge compression ignition (HCCI) engine combustion simulations of butanol isomers/nheptane mixtures. HCCI experiments fueled with butanol isomer/n-heptane m...

Species of arsenic and selenium thought to be present in coal combustion flue gases were studied using density functional theory and a broad range of ab initio methods. At each level of theory, the calculated geometries and vibrational frequencies of each species as well as the reaction enthalpies of anticipated reactions were compared with experimental data where available. Comparisons between...

Introduction In an effort to reduce pollutant emissions and increase energy efficiency, current clean combustion devices rely on precise control of reaction parameters such as fuel injection rate and reactant mixing. In order to understand, and predict, the effect of these parameters on the overall combustion process, temporallyand spatially-resolved measurements of key thermodynamic properties...

The chlorine content of municipal solid waste (MSW) and refuse derived fuel (RDF) plays a dominant role in combustion processes. In order to prevent operational problems, such as high temperature corrosion, quality assured analytical methods for the determination of the chlorine concentration are necessary. This paper presents results of the chlorine content of the main components of untreated ...

Detailed chemical kinetics is an integral component for predictive simulation of turbulent flames and is important for reliable prediction of flames and emissions. Major challenges of incorporation of detailed chemistry in flame simulations are induced by the large number of chemical species and the wide range of timescales involved in detailed kinetics. In this work, dynamic adaptive chemistry...

On the basis of the stochastic reactor model Partially Stirred Plug Flow Reactor (PaSPFR) a model is developed that accounts for soot and NOx formation in the distributed combustion regime. This is done by means of the joint composition probability density function (PDF). The composition vector consists of the species mass fraction in the gas phase, enthalpy, and four moments of the soot partic...

Tunable Diode Laser Absorption Tomography (TDLAT) is a non-intrusive measurement technique for determining two-dimensional spatially resolved distributions of temperature and species concentration in high enthalpy flows. TDLAT combines infrared laser absorption spectroscopy with tomographic image reconstruction. The TDLAT technique has been implemented at the University of Virginia's Aerospace ...

The Thermogravimetric Analysis (TGA) techniques and concretely the study of the burning profile provide information that can be used to estimate the behaviour of the combustion of carbonous materials. Commonly, these techniques have been used for the study of carbons, but are also interesting for the analysis of biomass wastes, due to the different species present on the wastes affect directly ...

Simultaneous monitoring of multiple combustion intermediates using femtosecond filament-induced nonlinear spectroscopy is demonstrated. Clean fluorescence emissions from free radicals CH, CN, NH, OH, and C(2), as well as atomic C and H, are observed when a femtosecond filament is formed in the laminar ethanol/air flame on an alcohol burner. The fluorescence signals of these species are found to...