Constructing hierarchical and ultrathin-structured metal sulfides is beneficial for achieving high-efficiency hydrogen evolution catalysts. Herein, ZnIn2S4 (ZIS) hollow nanoflowers (HNFs) composed of ultrathin nanosheets are creatively synthesized via a facile trisodium citrate-mediated stirring-assisted solvothermal method. Experimental results reveal that the synergy effect ethanol, citrate, ...