OBJECTIVES The inspiration of cobalt containing dust leads to various respiratory symptoms, including asthma and interstitial lung disease. Occupational asthma caused by cobalt chloride has been diagnosed in a 35-year-old patient, who worked as a diamond polishing disc former. The patient presented a 2-year history of dyspnea, cough and symptoms of rhinitis. MATERIALS AND METHODS The patient ...

Zn0.9Cd0.1S nanoparticles doped with 0.005-0.24 M cobalt have been prepared by co-precipitation technique in ice bath at 280 K. For the cobalt concentration >0.18 M, XRD pattern shows unidentified phases along with Zn0.9Cd0.1S sphalerite phase. For low cobalt concentration (≤0.05 M) particle size, dXRDis ~3.5 nm, while for high cobalt concentration (>0.05 M) particle size decreases abruptly (~2...

to cobalt with negative results for chromium, nickel and cement. Both prostheses were removed and the joints were sterile but contained grey pultaceous material with a relatively high cobalt and chromium content; there were multiple acetabular fractures on each side and the acetabular wall was paper-thin. Following the removal of the second prosthesis she became cobalt-negative and her urinary ...

The addition of cobalt was experimentally observed to increase the strength and impact toughness of Cu precipitation hardened steel. In order to understand the mechanism of this strengthening, we studied the effect of cobalt in the bulks and surfaces of bcc Fe and bcc Cu, as well as at the Fe/Cu interface by ab initio density-functional approach. We investigated the cobalt distribution between ...

Monodisperse cobalt nanoparticles (NPs) are synthesized via a high-temperature thermal decomposition method in the presence of oleic acid and triphenylphosphine. The as-synthesized NPs are stable against further deep oxidation when they are kept in heptane (C7H16). Time-dependent x-ray photoelectron spectroscopy studies indicate that the oxidation of the as-synthesized cobalt NPs by air is slow...

In contrast to the majority of related experiments, which are carried out in organic solvents at high temperatures and pressures, cobalt nanowires were synthesized by chemical reduction in aqueous solution with the assistance of polyvinylpyrrolidone (PVP) as surfactant under moderate conditions for the first time, while an external magnetic field of 40 mT was applied. Uniform linear cobalt nano...

Cobalt can mimic hypoxia and has been implicated as a cause of lung defects. However, the effect of cobalt on airway smooth muscle (ASM) cells has not been analyzed in detail. In this article, we use primary cultures of ASM cells from rabbit trachea and show that exposure to cobalt chloride causes a rapid increase of the intracellular levels of hypoxia-inducible factor-1alpha, which is detected...

The development of efficient and stable water oxidation catalysts is necessary for the realization of practically viable water-splitting systems. Although extensive studies have focused on the metal-oxide catalysts, the effect of metal coordination on the catalytic ability remains still elusive. Here we select four cobalt-based phosphate catalysts with various cobalt- and phosphate-group coordi...

We demonstrated that single-crystalline cobalt monoxide (CoO) hollow spheres and octahedra could be selectively synthesized via thermal decomposition of cobalt(II) acetylacetonate in 1-octadecene solvent in the presence of oleic acid and oleylamine. The morphologies and sizes of as-prepared CoO nanocrystals could be controlled by adjusting the reaction parameters. Cobalt oxide (Co(3)O(4)) hollo...