To support EU policy, indicators of pesticide leaching at the European level are required. For this reason, a metamodel of the spatially distributed European pesticide leaching model EuroPEARL was developed. EuroPEARL considers transient flow and solute transport and assumes Freundlich adsorption, first-order degradation and passive plant uptake of pesticides. Physical parameters are depth depe...

The bioleaching of metal sulfide has developed into a very important industrial process and understanding the microbial dynamic is key to advancing commercial bioleaching operations. Here we report the first quantitative description of the dynamic of active communities in an industrial bioleaching heap. Acidithiobacillus ferrooxidans was the most abundant during the first part of the leaching c...

An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.

Assessing the behaviour of organic chemicals in soil is a complex task as it is governed by the physical chemical properties of the chemicals, the characteristics of the soil as well as the ambient conditions of the environment. The chemical partitioning space, defined by the air-water partition coefficient (K(AW)) and the soil organic carbon-water partition coefficient (K(OC)), was employed to...

Incineration is a widely used and well established technology for the municipal solid waste (MSW) management. Modern MSW incineration plants are equipped with improved air pollution control (APC) systems, which reduce pollutants well below the established limits. The environmental concern has, thus, moved from the air emissions to the solid residues generated from the APC systems of the inciner...

Lithium is becoming a strategic metal due to its important applications in secondary battery electrodes used in electronic appliances and also in electric traction vehicles. Lithium primary resources are brines and rock minerals, the former being nowadays almost exclusively used in the production of lithium commodities. With the expected increase in lithium demand, the development of competitiv...

The effect of metabolites from the indigenous Acidithiobacillus thiooxidans and temperature on the bioleaching of cadmium from soil was investigated in the present study. Bioleaching was found to be more effective than chemical leaching of cadmium. The metabolite, mainly sulfuric acid, which was shown to be growth-associated in the exponential phase, plays a major role in bioleaching. The maxim...

Base metal sulphides are an important source of various metals. They are typically intergrowth and due to the complex nature of their ores, the hydrometallurgical technique is the very convenient way of extracting the desired component. If it is possible to extract the metal from an ore selectively, the subsequent processing steps become less complicated. Mechanical activation seems to be a fav...

Many coal-fired power plants are implementing ammonia-based technologies to reduce NO(x) emissions. Excess ammonia in the flue gas often deposits on the coal fly ash. Ammonia can form complexes with many heavy metals and change the leaching characteristics of these metals. This research tends to develop a fundamental understanding of the ammonia impact on the leaching of some heavy metals, exem...