Three CuO/CeO2 catalyst with different morphologies of ceria, namely nanospheres, nanorods and nanocubes, were synthesized and used to catalyze the water-gas shift (WGS) reaction. The reactivity tests showed that the Cu supported on the ceria nanospheres exhibited both the highest activity and superior stability when compared with the nanocube and nanorod ceria catalysts. Operando X-ray diffrac...

An important part of fundamental research in catalysis is based on theoretical and modeling foundations which are closely connected with studies of single-crystalline catalyst surfaces. These so-called model catalysts are often prepared in the form of epitaxial thin films, and characterized using advanced material characterization techniques. This concept provides the fundamental understanding ...

Cu-based, solid oxide fuel cell (SOFC) electrodes were modified by electrodeposition of Co. The addition of only 5-vol% Co by electrodeposition significantly improved the thermal stability compared to either Cu-ceriaYSZ, Cu-Co-ceria-YSZ, or Co-ceria-YSZ electrodes prepared only by impregnation with much higher metal loadings, demonstrating that electrodeposited metal layers form metal films wit...

Beyond the traditional use of ceria as an abrasive, the scope of nanoceria applications now extends into fuel cell manufacturing, diesel fuel additives, and for therapeutic intervention as a putative antioxidant. However, the biological effects of nanoceria exposure have yet to be fully defined, which gave us the impetus to examine its systemic biodistribution and biological responses. An exten...

In recent years, nanostructured Au catalysts have attracted a lot of attention as potential candidates for the removal of poisonous carbon monoxide from synthesis gas streams, thus upgrading hydrogen gas to be used as fuel at the anode of lowtemperature fuel cells. The interest in Au nanoparticles has been motivated by the pioneering work of Haruta et al., who demonstrated the extremely high ac...

Nano-sized particles of ceria with high surface area were processed by solution combustion synthesis (SCS) and their catalytic activity towards combustion of carbonaceous materials was compared with that obtained by simple thermal decomposition of cerium nitrate, exhibiting the same specific surface area. These two kinds of ceria powders were tested, by DTA and temperature programmed combustion...

The objective was to characterize the biodistribution of nanoscale ceria from blood and its effects on oxidative stress endpoints. A commercial 5% crystalline ceria dispersion in water (average particle size 3194 nm) was infused intravenously into rats (0, 50, 250 and 750 mg/kg), which were terminated 1 or 20 h later. Biodistribution in rat tissues was assessed by microscopy and ICP-AES/MS. Oxi...

Supercritical growth: The formation and evolution of ceria nanoparticles during hydrothermal synthesis was investigated by in situ total scattering and powder diffraction. The nucleation of pristine crystalline ceria nanoparticles originated from previously unknown cerium dimer complexes. The nanoparticle growth was highly accelerated under supercritical conditions.

Ceria and nickel-doped ceria necklace-like nanowires were synthesized by a facile, surfactant free method, through an unconventional assembly route. Homogeneous doping of lower-valent cations introduces elastic strain, resulting in extrinsic surface defects and higher catalytic performance in CO oxidization.

(22 articles) energy (149 articles) materials science collections Articles on similar topics can be found in the following Email alerting service here in the box at the top right-hand corner of the article or click Receive free email alerts when new articles cite this article-sign up We present a comprehensive thermodynamic and kinetic analysis of the suitability of cerium oxide (ceria) for the...