Time dependent density functional theory (TDDFT) and the conductor-like screening model (COSMO) of solvation were used to model the specific rotation and optical rotatory dispersion (ORD) of alanine, proline and serine solutions. Zwitterionic, cationic and anionic forms of amino acids were investigated and the results compared with experimental literature data obtained in neutral, acidic and ba...

mg(oh)2 nanoparticles were synthesized by a rapid microwave reaction. the effect of sodium dodecyl sulfonate (sds as anionic surfactant) and cetyl tri-methyl ammonium bromide (ctab as cationic surfactant) on the morphology of magnesium hydroxide nanostructures was investigated. multi wall carbon nano tubes was organo-modified for better dispersion in cellulose acetate matrix. the influence of m...

We have used magnetic relaxation dispersion to study bovine pancreatic trypsin inhibitor (BPTI) self-association as a function of pH, salt type and concentration, and temperature. The magnetic relaxation dispersion method sensitively detects stable oligomers without being affected by other interactions. We find that BPTI decamers form cooperatively under a wide range of solution conditions with...

in order to prepare polyurethane elastomers with acceptable physical properties and good biocompatibility, novel polyurethane networks were synthesized via curing reaction of epoxy-terminated polyurethane prepolymers (eups) with hexamethylene diamine. eups were prepared from reaction of glycidol with nco-terminated polyurethanes (itps). itps were also synthesized from reaction of one equivalent...

CONTEXT Condoms made of latex are not comfortable or appropriate for all consumers. Polyurethane condoms may provide a needed alternative. METHODS In a double-masked study, 805 monogamous couples were randomized to use either the polyurethane condom or the latex condom for six months. Couples recorded the frequency of intercourse, of condom use and of breakage and slippage throughout the tria...

BACKGROUND Polyurethane coating of breast implants has been shown to reduce capsular contracture in short-term follow-up studies. This 30-year study is the longest examination of the use of polyurethane-coated implants and their correlation with capsular contracture. METHODS This study evaluates the senior surgeon's (F.D.P.) experience with the use of polyurethane-coated implants in aesthetic...

BACKGROUND This study examined the effects of electrically conductive materials made from electrospun single- or multiwalled carbon nanotubes with polyurethane to promote myoblast differentiation into myotubes in the presence and absence of electrical stimulation. METHODS AND RESULTS After electrical stimulation, the number of multinucleated myotubes on the electrospun polyurethane carbon nan...

CONTEXT Although the first commercial polyurethane condom was approved for use several years ago, no U.S. clinical trial has compared its performance to that of the latex condom. METHODS In a masked crossover study, 360 couples were randomized to use three polyurethane condoms and three latex condoms. After each use, couples recorded condom breaks, condom slips and other aspects of performanc...