Bunsen reaction was performed electrochemically using cation exchange membranes prepared by a radiation-induced grafting method for application to the iodine-sulfur thermochemical water-splitting cycle. The reaction experiments using sulfuric acid dissolving sulfur dioxide as the anolyte and hydriodic acid dissolving iodine as the catholyte verified the progress of the aimed reaction. Compared ...

One-step purification and desalination The of water for drinking purposes can require multiple filtration steps technologies to remove contaminants such as salts heavy metals. Some could have value if recovered, but these are often discharged in the waste streams. Uliana et al. describe a general approach fabrication robust, tunable, adsorptive membranes through incorporation porous aromatic fr...

Most commercial anion exchange membranes (AEMs) deploy quaternary ammonium moieties. Alternative cation moieties have been explored in AEMs for fuel cells, but there are no studies focused examining alternative tethered cations ionic separations—such as organic acid transport via electrodialysis. H-cell and conductivity experiments demonstrate that benzyl 1-methyl imidazolium groups polysulfone...

A new method for the speciation of ng/mL concentrations of Cr(III) and Cr(VI) solutions with analysis by laser-induced breakdown spectroscopy (LIBS) is reported. Speciation is achieved by pre-concentration of the chromium onto commercially available cation exchange polymer membranes. Chromium(III) is removed directly by cation exchange; chromium(VI) in the filtrate is reduced to Cr(III) and con...