At room temperature, the enhanced effect of water vapor on ozone catalytic oxidation (OZCO) of formaldehyde to CO2 over MnOx catalysts and the reaction stability was reported. In a dry air stream, only below 20% of formaldehyde could be oxidized into CO2 by O3. In humid air streams (RH≥55%), ∼100% of formaldehyde were oxidized into CO2 by O3 and the reaction stability was significantly enhanced...

Marine reserves are becoming progressively more important as anthropogenic impacts continue to increase, but we have little baseline information for most marine environments. In this study, we focus on the Oceanic Shoals Commonwealth Marine Reserve (CMR) in northern Australia, particularly the carbonate banks and terraces of the Sahul Shelf and Van Diemen Rise which have been designated a Key E...

The differentiation of stem cells into multi-lineages is essential to aid the development of tissue engineered materials that replicate the functionality of their tissue of origin. For this study, Raman spectroscopy was used to monitor the formation of a bone-like apatite mineral during the differentiation of human mesenchymal stem cells (hMSCs) towards an osteogenic lineage. Raman spectroscopy...

The deactivation of Au/CeO2 catalysts during low-temperature water–gas shift reaction and the underlying physical origin were investigated, comparing the deactivation in different reaction atmospheres and subsequent regeneration of the catalysts by reactive treatment in O2/N2 or H2O/N2 gas mixtures. Based on TEM and XRD measurements, Au and ceria particle sintering (irreversible deactivation) c...

Recent experimental evidence and computer modeling have shown that the crystallization of a range of minerals does not necessarily follow classical models and theories. In several systems, liquid precursors, stable pre-nucleation clusters and amorphous phases precede the nucleation and growth of stable mineral phases. However, little is known on the effect of background ionic species on the for...

Ocean acidification causes biodiversity loss, alters ecosystems, and may impact food security, as shells of small organisms dissolve easily in corrosive waters. There is a suggestion that photosynthetic organisms could mitigate ocean acidification on a local scale, through seagrass protection or seaweed cultivation, as net ecosystem organic production raises the saturation state of calcium carb...

Carbonate in its various forms is an important component in blood and the cytosol. Since, under conditions that simulate therapy, carbonate reacts with cisplatin to form carbonato complexes, one of which is taken up and/or modified by the cell [C.R. Centerwall, J. Goodisman, D.J. Kerwood, J. Am. Chem. Soc., 127 (2005) 12768-12769], cisplatin-carbonato complexes may be important in the mechanism...

The zooplankton community structure in Eğirdir Lake (Isparta-Turkey) was studied monthly throughout an annual cycle (January 2010-December 2010). The zooplankton community was represented by three main groups: Rotifera, Cladocera and Copepoda, respectively comprised 89.62%, 7.78% and 2.60% of the total zooplankton abundance. Eğirdir Lake was dominated by the rotifera Polyarthra dolichoptera in ...

21 Marine calcifiers are amongst the most vulnerable organisms to ocean acidification 22 due to reduction in the availability of carbonate ions for skeletal/shell deposition. 23 However, there are limited long-term studies on the possible impacts of increased 24 pCO2 on these taxa. A 7 month CO2 perturbation experiment was performed on one 25 of the most calcium carbonate dependent species, the...