Geochemical reactions may alter the permeability of leakage pathways in caprocks, which serve a critical role in confining CO2 in geologic carbon sequestration. A caprock specimen from a carbonate formation in the Michigan sedimentary Basin was fractured and studied in a high-pressure core flow experiment. Inflowing brine was saturated with CO2 at 40°C and 10 MPa, resulting in an initial pH of ...

S ince the beginning of the Christian era, the Apuanian Alps between the provinces of Massa Carrara and Lucca in Tuscany, have been a centre for the excavation of white marble, venato and arabescato, and Cardoso stone. Marble is a metamorphic rock composed of calcium carbonate with a quartz content of less than 1%. Cardoso stone (from the name of the village of Cardoso) is a dark grey metamorph...

It is widely recognized that carbonic anhydrase (CA) participates in silicate weathering and carbonate formation. Nevertheless, it is still not known if the magnitude of the effect produced by CA on surface rock evolution changes or not. In this work, CA gene expression from Bacillus mucilaginosus and the effects of recombination protein on wollastonite dissolution and carbonate formation under...

With the aim of elucidating the details of enhanced oil recovery by surfactant solution flooding, we have determined the detailed behaviour of model systems consisting of a packed column of calcium carbonate particles as the porous rock, n-decane as the trapped oil and aqueous solutions of the anionic surfactant sodium bis-2-ethylhexyl sulfosuccinate (AOT). The AOT concentration was varied from...

Carbonate reservoirs, accounting for majority of the world’s hydrocarbon reserves, are well known for their heterogeneity and multiscale pore characteristics. The pore sizes in carbonate rock can vary over orders of magnitudes, the geometry and topology parameters of pores at different scales have a great impact on flow properties. A relatively simple way to integrate a set of digital pore spac...

Carbonates of the Ojo Huelos Member of the San Pedro Arroyo Formation include ostracodal limestones, brecciated micritic limestones, vuggy, mottled limestones, peloidal graistones/packstones, pisolitic rudstones and nodular limestones. These lithofacies record deposition in lacustrine, palustrine and alluvial environments. Lacustrine (ostracodal) limestones are isotopically heaviest, with nodul...