one distinct concentration of copper ions was embedded into the silica matrix to xerogel form using copper source cu(no3)2∙3h2o. the xerogel samples were prepared with using hydrolysis and condensation reactions of tetraethyl ortho-silicate (teos) by the sol-gel method. in this investigation, new molar ratio of h2o/teos was determined to be 11.7. also, the necessary amount of tri-hydrated coppe...

The chemistry of tributyl phosphate on Fe3O4 was studied in ultrahigh vacuum using temperature-programmed desorption (TPD) and Auger spectroscopy. A portion of the tributyl phosphate desorbs intact with an activation energy of 120 kJ/mol. The remainder decomposes either by PAO bond scission to deposit surface butoxy species or appears to dehydrogenate desorbing C2 or C3 compounds and depositing...

This study reports the competitive adsorption of Ni(II), Cd(II) and Cr(VI) onto sunflower waste biomass carbons, viz. sunflower head carbon and sunflower stem carbon from multi-metal aqueous solution. The adsorption capacity of the adsorbents was highest in mono-metal system but decreased with increase in the number of coions. The adsorption capacity in mono-metal system was 0.32 and 0.45 mM/g ...

We present results of studies carried out from 2007 to 2020 on the assessment emission main greenhouse gases: carbon dioxide, monoxide, methane, nitrous oxide, mono- and nitrogen emitted during top bottom fires in forests Republic Crimea.
 The aim work was monitor gas emissions as a result according ground-based peninsula.
 Materials methods. objects study were uneven-aged burnt pine ...

An activated carbon supported α-molybdenum carbide catalyst (α-MoC1-x/AC) showed remarkable activity in the selective deoxygenation of guaiacol to substituted mono-phenols in low carbon number alcohol solvents. Combined selectivities of up to 85% for phenol and alkylphenols were obtained at 340 °C for α-MoC1-x/AC at 87% conversion in supercritical ethanol. The reaction occurs via consecutive de...

Mono-[125I]iodo- alpha - bungarotoxin - receptor complexes extracted from chick myotube cultures as well as from adult denervated extensor digitorum longus muscles of the mouse have been banded at their buoyant density in gradients of metrizamide-deuterium oxide. When cultures or denervated adult muscles are preincubated in media containing 2H- or 13C-substituted amino acids under conditions of...

TiO2 thin films have been prepared by the sol-gel dipcoating technique in order to elaborate antireflective thin films for monocrystalline silicon (mono-Si). The titanium isopropoxyde was chosen as a precursor with hydrochloric acid as a catalyser for preparing a stable solution. The optical properties have been tailored with varying the solution concentration, the withdrawn speed, and the heat...

The authors report on a new method for the synthesis of graphene, a mono-layer of carbon atoms arranged in a honey comb lattice, and the assessment of the properties of obtained graphene layers using micro-Raman characterisation. Graphene was produced by a high pressure–high temperature (HPHT) growth process from the natural graphitic source material by utilising the molten Fe–Ni catalysts for ...

A modification of the Haldane technique, using potassium hydroxide as the absorbent, was devised to measure the concentration of carbon dioxide in the presence of nitrous oxide. It depends upon the principle that the amount of nitrous oxide absorbed is proportional to the duration of its exposure to the reagent. If the absorption of carbon dioxide from the gas mixture is completed within a fixe...