Through the incorporation of a thiophene functionality, a novel solution-processable small organic chromophore was designed, synthesized and characterized for application in bulk-heterojunction solar cells. The new chromophore, (2Z,2'Z)-2,2'-(1,4-phenylene)bis(3-(5-(4-(diphenylamino)phenyl)thiophen-2-yl)acrylonitrile) (coded as AS2), was based on a donor-acceptor-donor (D-A-D) module where a si...

Abstract Organic solar cell (OSC) is one of the best promising candidate for harvesting energy mainly due to their simple and economic fabrication process, reduced manufacturing cost, easy integration other products. Bulk heterojunction in which active layer a blend donor –acceptor materials are organic photovoltaic device with highest efficiency significant improvement performance occur over l...

A key parameter to improve the performance of organic solar cells is the optimization of electronic phenomena at donor–acceptor interfaces through the optimization of the morphology of the bulk heterojunction. The correlative mapping of morphological, electrical and mechanical properties at the nanoscale by advanced scanning probe microscopy techniques allows for a detailed characterization of ...

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Nanoscale morphology has been shown to be a critical parameter governing charge transport properties of polymer bulk heterojunction (BHJ) solar cells. Recent results on vertical phase separation have intensified the research on 3D morphology control. In this paper, we intend to modify the distribution of donors and acceptors in a classical BHJ polymer solar cell by making the active layer riche...

By charge neutralization of carboxylic acid groups in graphene oxide (GO) with Cs(2)CO(3) to afford Cesium-neutralized GO (GO-Cs), GO derivatives with appropriate modification are used as both hole- and electron-extraction layers for bulk heterojunction (BHJ) solar cells. The normal and inverted devices based on GO hole- and GO-Cs electron-extraction layers both outperform the corresponding sta...

The use of a p-type inorganic semiconductor to form a nanorod scaffold within a polymer-fullerene bulk heterojunction solar cell is reported. The performance of this cell is compared to those made of the commonly used n-type scaffold of ZnO, which has been reported many times in the literature. The scaffold is designed to improve charge-carrier collection by increased mobility in thicker sample...

Bodipy-based polymers, which possess a high absorption coefficient with a bandgap of approximately 1.6 eV, have been used as electron donor in solution-processed bulk heterojunction (BHJ) solar cells containing PCBM as acceptor. A power conversion efficiency (PCE) of approximately 2% has been achieved with V(oc) of approximately 0.8 eV and J(sc) of approximately 4.8 mA cm(-2).