This paper reports an economic, simple, and rapid FI-CL method for the determination of MCPA. This method requires simple instrumentation and it is fast enough to be used in routine analyses. A chemiluminescence signal is generated by reaction between photodegraded MCPA and ferricyanide solution in alkaline medium. All physical and chemical parameters in the flow injection chemiluminescence sys...

Sorption of four herbicides and a metabolite of indaziflam on a fresh macadamia nut biochar and biochars aged one or two years in soil was characterized. On fresh biochar, the sorption was terbuthylazine (Kd = 595) > indaziflam (Kd = 162) > MCPA (Kd = 7.5) > fluoroethyldiaminotriazine (Kd = 0.26) and nicosulfuron (Kd = 0). Biochar surface area increased with aging attributed to the loss of a su...

While they had failed to solve the mystery, we showed clearly that the disease is an encephalopathy, associated with hypoglycemia, hence metabolic, and not infectious [2]. We found strong epidemiological association of the disease with litchi fruit [2]. The manifestations are similar to hypoglycemic encephalopathy caused by methylene cyclopropylalanine (MCPA) present in ackee fruit; ackee and l...

Isoprene (2-methyl-1,3-butadiene) protection against effects of singlet oxygen was investigated in Myrtus communis and Rhamnus alaternus. In M. communis, singlet oxygen produced in the leaves by Rose Bengal (RB) led to a 65% decrease in net assimilation rates within 3 h, whereas isoprene emission rates showed either a 30% decrease at ambient CO2 concentrations or a 70% increase under high CO2. ...

Registered dose of herbicides may be higher than rate required for controlling weed species depending on growth stages. In order to study the effect of individual post-emergence application of 2,4-D plus MCPA and three sulfonylurea herbicides at four- to six-true leaf stage of weeds, experiments were conducted in 2011 at the greenhouse of Agricultural Faculty of Ferdowsi University of Mashh...

Hypoglycin A (HGA) in seeds of Acer spp. is suspected to cause seasonal pasture myopathy in North America and equine atypical myopathy (AM) in Europe, fatal diseases in horses on pasture. In previous studies, this suspicion was substantiated by the correlation of seed HGA content with the concentrations of toxic metabolites in urine and serum (MCPA-conjugates) of affected horses. However, seed ...

Biochar, the solid residual remaining after the thermochemical transformation of biomass for carbon sequestration, has been proposed to be used as a soil amendment, because of its agronomic benefits. The effect of amending soil with six biochars made from different feedstocks on the sorption and leaching of fluometuron and 4-chloro-2-methylphenoxyacetic acid (MCPA) was compared to the effect of...

Industries such as manufacturing, mining, and transportation have been experiencing mechanization and automation for well over 100 years. Agriculture, in contrast, has lagged behind and only in the last 30 years have these processes been adopted. Long considered a way of life rather than an industry, farming is now becoming as highly industrialized as the traditionally organized businesses. Pes...

Pesticides and their residues frequently contaminate surface waters and groundwater so consequently there is a great need to identify methods and practices that reduce such contamination. This thesis examined the potential of a ‘bioprophylactic’ concept based on the hypothesis that diffuse contamination after application in the field can be significantly reduced if pesticides are degraded as ra...