نتایج جستجو برای: brönsted acidic ionic liquids

تعداد نتایج: 93993  

In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easi...

Journal: :IOP Conference Series: Materials Science and Engineering 2013

Journal: :physical chemistry research 2014
razieh jalal elaheh k. goharshadi hashem sajjadi paul nancarrow

the antibacterial activity of a series of ionic liquids containing short-chained 1-alkyl-3-methylimidazolium cations ([cnmim+]; n = 2, 4, 6 and 8) and bis (trifluoromethylsulfonyl) imide anion ([tf2n]) against e. coli and b. subtilis was measured, for the first time. all ils used in this work were synthesized and analyzed by fourier transform infrared (ft-ir) spectroscopy, nmr, and karl-fischer...

Journal: :Chemphyschem : a European journal of chemical physics and physical chemistry 2012
Seiji Tsuzuki

The development of ionic liquids with low viscosity and high ionic conductivity is important for many applications of ionic liquids, such as their use as electrolytes for electronic devices. The transport properties depend on the motion of ions in ionic liquids. The viscosity becomes low and the ionic conductivity becomes high as the diffusion of ions becomes fast. Therefore the elucidation of ...

In recent years there has been a great deal of attention paid by researchers in investigating ionic liquids (ILs) mainly due to the tremendous potential that ionic liquids have in reaction and separation technology. Sonic speed is an important thermodynamic property of ionic liquids (ILs) and always chosen as a source to determine other properties. A database for the sonic speed of pure ILs cre...

Journal: :Chemical communications 2017
Matthew A Gebbie Alexander M Smith Howard A Dobbs Alpha A Lee Gregory G Warr Xavier Banquy Markus Valtiner Mark W Rutland Jacob N Israelachvili Susan Perkin Rob Atkin

Ionic liquids are pure salts that are liquid under ambient conditions. As liquids composed solely of ions, the scientific consensus has been that ionic liquids have exceedingly high ionic strengths and thus very short Debye screening lengths. However, several recent experiments from laboratories around the world have reported data for the approach of two surfaces separated by ionic liquids whic...

2013
Weiguo Cheng Qian Su Jinquan Wang Jian Sun

This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ionic liquids, the catalytic system of hydrogen bond-promoted ionic liquids and supported ionic liquids. Metal and ionic liquids show a synergistic ef...

Journal: :Physical chemistry chemical physics : PCCP 2013
Gitanjali Rai Anil Kumar

The present communication divulges interesting thermal behavior of different protic ionic liquids arising due to the hydrophobicity modifications in their parent cationic ring structures. This work assists us in differentiating between protic ionic liquids, their aprotic counterparts and common electrolytes in water. The thermal signatures produced by protic ionic liquids, aprotic ionic liquids...

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