Industry has long used charcoal or other solid absorbents in columns for cleaning gas streams or for solvent recovery, and more recently Turner (1943), Claesson (1946), Glueckauf, Barker & Kitt (1949), Phillips (1949) and Turkel'taub (1950) have used charcoal in gas chromatograms for the analysis of hydrocarbons and esters. Gas-liquid scrubbing columns have been used in industry for many years ...

Biodiesel production through chemical interesterification of triglycerides requires an excess methyl acetate that must be recovered once the reaction is finished and catalyst neutralized. The present study concerns with purification by pervaporation. PERVAP 2201 was chosen as pervaporation membrane due to its high hydrophilic character makes it suitable for elimination water in acetate. Runs we...

Dimethyl amino ethyl azide (DMAZ) is a good replacement for hydrazine group in space programs. This chemical was purified from water (1) + DMAZ (2) mixture in sub-atmospheric distillation column due to thermal sensitivity of DMAZ. For designing of the column, it is necessary to have vapor-liquid equilibrium data. In this article, T-x,y and y-x diagrams were obtain...

In this work we investigate the critical line of binary azeotropic mixtures of acetone-n-pentane. We pinpoint the abnormal behavior of the critical density line as a function of the mole fraction of one of the component and show its influence on other thermodynamic properties such as the volume, the enthalpy and the entropy.

Ionic liquids (ILs) have shown excellent performance in the separation of binary azeotropes through extractive distillation [1]. But role ionic liquid azeotropic system is not well understood. In this paper, COSMO-RS model was applied to screen an appropriate IL separate azeotrope ethyl acetate (EA) and ethanol 1-octyl-3-methylimidazolium tetrafluoroborate ([OMIM][BF4]) selected. The Quantum Me...

1,3-butadiene, bd is produced from c4-cut by extractive distillation. the separation of 1,3-butadiene from c4-cut is not possible through the conventional distillation processes, because several mixtures have consisted of close boiling points constituents and make azeotrope. the basf extraction distillation process in bd unit of jam and amirkabir petrochemical company improves the relative vola...

This study presents the analysis of exergy load distribution in a separation process by extractive distillation for ethanol dehydration. The methodology carried out is divided into three parts: calculation flow considering physical and chemical exergies process; primary transformed contributions consumed exergy; finally, overall efficiency, which shows real percentage energy being used process....